Bismuth nitrate pentahydrate
Synonym(s):Bismuth trinitrate pentahydrate;Bismuth(III) nitrate
- CAS NO.:10035-06-0
- Empirical Formula: BiH10N3O14
- Molecular Weight: 485.07
- MDL number: MFCD00149157
- EINECS: 600-076-0
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-10-29 11:48:30
What is Bismuth nitrate pentahydrate?
Chemical properties
White Crystal
Physical properties
Lustrous triclinic crystals; acid taste; hygroscopic; density 2.83 g/cm3; decomposes at 75°C; reacts slowly with water; soluble in acids and acetone; insoluble in alcohol.
The Uses of Bismuth nitrate pentahydrate
Luminous paints, preparation of bismuth saltsBismuth(III) nitrate pentahydrate is an oxidant for a variety of 4-substituted Hantzsch 1,4-dihydropyridines. It also serves as a reagent for selective oxidation of sufides to sulfoxides. Further, it is involved in the preparation of Dragendorff reagent and used as a TLC stain. It is also used to prepare other bismuth compounds.
The Uses of Bismuth nitrate pentahydrate
An excellent oxidant for a variety of 4-substituted Hantzsch 1,4-dihydropyridines.1 Convenient reagent for selective oxidation of sufides to sulfoxides.2
The Uses of Bismuth nitrate pentahydrate
Bismuth Nitrate Pentahydrate acts as a precursor in the prepoaration of photocatalysts.
What are the applications of Application
Bismuth(III) nitrate pentahydrate is an excellent oxidant for a variety of 4-subsituted Hantzsch 1,4-dihydropyridines
Preparation
Bismuth nitrate is prepared by dissolving bismuth in concentrated nitric acid, followed by evaporation and crystallization .
General Description
Bismuth(III) nitrate pentahydrate is a non-toxic, inexpensive, easy to handle and air insensitive reagent, commonly used in organic synthesis with a wide range of applications.
Properties of Bismuth nitrate pentahydrate
Melting point: | 30 °C(lit.) |
Boiling point: | 75-80 °C(lit.) |
Density | 2,83 g/cm3 |
solubility | Soluble in dilute nitric acid solution, dilute acetic acid, glycerol and acetone. Insoluble in alcohol, ethyl acetateSoluble in acetone, acetic acid and glycerol. Insoluble in ethanol and ethyl acetate. |
form | Solid |
color | White |
Specific Gravity | 2.83 |
Odor | Slight nitric acid odor |
Water Solubility | MAY DECOMPOSE |
Sensitive | Hygroscopic |
Merck | 14,1271 |
Stability: | Stable. Incompatible with strong acids, strong reducing agents, organic materials, finely powdered metals, moisture. Strong oxidizer. |
InChI | InChI=1S/Bi.3NO3.5H2O/c;3*2-1(3)4;;;;;/h;;;;5*1H2/q+3;3*-1;;;;; |
CAS DataBase Reference | 10035-06-0(CAS DataBase Reference) |
Safety information for Bismuth nitrate pentahydrate
Signal word | Danger |
Pictogram(s) |
Flame Over Circle Oxidizers GHS03 Corrosion Corrosives GHS05 |
GHS Hazard Statements |
H272:Oxidising liquids;Oxidising solids H318:Serious eye damage/eye irritation |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P220:Keep/Store away from clothing/…/combustible materials. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P370+P378:In case of fire: Use … for extinction. P501:Dispose of contents/container to..… |
Computed Descriptors for Bismuth nitrate pentahydrate
InChIKey | FBXVOTBTGXARNA-UHFFFAOYSA-N |
SMILES | [N+]([O-])([O-])=O.[N+]([O-])([O-])=O.[N+]([O-])([O-])=O.O.O.O.O.O.[Bi+3] |
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