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HomeProduct name listCobaltous nitrate hexahydrate

Cobaltous nitrate hexahydrate

Synonym(s):Cobalt(II) nitrate hexahydrate;Cobaltous nitrate;Cobaltous nitrate hexahydrate;Nitric acid, cobalt(II) salt

  • CAS NO.:10026-22-9
  • Empirical Formula: CoH12N2O12
  • Molecular Weight: 291.03
  • MDL number: MFCD00149647
  • EINECS: 600-049-3
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-05-08 14:48:35
Cobaltous nitrate hexahydrate Structural

What is Cobaltous nitrate hexahydrate?

Chemical properties

Red crystal, deliquescent in most air

The Uses of Cobaltous nitrate hexahydrate

Preparation of cobalt standard solutions.

The Uses of Cobaltous nitrate hexahydrate

manufacture of cobalt pigments and invisible inks; decorating stoneware and porcelain; preparation of catalysts; production of vitamin B12 supplements.

The Uses of Cobaltous nitrate hexahydrate

Cobaltous nitrate [Co(NO3)2·6H2O], also known as cobalt nitrate, is a red crystal that absorbs moisture. It is used in inks, pigments, animal feed, soil enhancers, and hair dyes.

What are the applications of Application

Cobalt(II) nitrate hexahydrate is a salt of Co(II) that acts as a source of Cobalt

Definition

ChEBI: A hydrate that is the hexahydrate form of cobalt dinitrate.

Preparation

The red hygroscopic hexahydrate Cu(NO3)2.6H2O crystallizes from aqueous solutions of cobalt bases in dilute nitric acid at room temperature. It becomes the trihydrate when heated at 56° ; at higher temperatures decomposition occurs.

General Description

Cobalt(II) nitrate hexahydrate (Co(NO3)2·6H2O) is the hydrated cobalt salt. Its step-wise thermal degradation has been investigated. It affords anhydrous cobalt(II)nitrate as decomposition product.

Purification Methods

Crystallise the nitrate from water (1mL/g), or ethanol (1mL/g), by partial evaporation. After 3 crystallisations from H2O it contains: metal (ppm) As (8), Fe (1.2), K (1), Mg (4), Mn (4), Mo (4), Na (0.6), Ni (18), Zn (1.6). The hexahydrate gives the pink anhydrous salt by the action of HNO3 and N2O5. The hexahydrate melts at ~55o to give a red liquid which decomposes on further heating at 100-105o to form Co3O4.

Properties of Cobaltous nitrate hexahydrate

Melting point: 55 °C(lit.)
Density  1.88
refractive index  1.52
storage temp.  Store at +5°C to +30°C.
solubility  2170g/l
form  Wet Crystalline Aggregates
color  Red to pinkish-brown
Specific Gravity 1.87
PH 4.0 (100g/l, H2O, 20℃)
Water Solubility  134 g/100 mL
Merck  14,2444
Exposure limits ACGIH: TWA 0.02 mg/m3
Stability: Stable. Strong oxidizer - incompatible with reducing agents.
CAS DataBase Reference 10026-22-9(CAS DataBase Reference)
EPA Substance Registry System Cobalt nitrate hexahydrate (10026-22-9)

Safety information for Cobaltous nitrate hexahydrate

Signal word Danger
Pictogram(s)
ghs
Flame Over Circle
Oxidizers
GHS03
ghs
Corrosion
Corrosives
GHS05
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
ghs
Environment
GHS09
GHS Hazard Statements H272:Oxidising liquids;Oxidising solids
H302:Acute toxicity,oral
H317:Sensitisation, Skin
H318:Serious eye damage/eye irritation
H334:Sensitisation, respiratory
H341:Germ cell mutagenicity
H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313:IF exposed or concerned: Get medical advice/attention.

Computed Descriptors for Cobaltous nitrate hexahydrate

InChIKey QGUAJWGNOXCYJF-UHFFFAOYSA-N

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