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HomeProduct name listBIS(CYCLOPENTADIENYL)COBALT

BIS(CYCLOPENTADIENYL)COBALT

  • CAS NO.:1277-43-6
  • Empirical Formula: C10H10Co10*
  • Molecular Weight: 189.12
  • MDL number: MFCD00013749
  • EINECS: 215-061-0
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-08-15 19:00:21
BIS(CYCLOPENTADIENYL)COBALT Structural

What is BIS(CYCLOPENTADIENYL)COBALT?

Chemical properties

dark violet crystals

The Uses of BIS(CYCLOPENTADIENYL)COBALT

Bis(cyclopentadienyl)cobalt is used to catalyze the preparation of pyridines from alkynes and nitriles. It acts as a polymerization inhibitor of olefins. It is a common one-electron reducing agent in the laboratory. It reacts with carbon monoxide to prepare cobalt(I) derivative, cyclopentadienylcobalt dicarbonyl. It also serves as an internal standard in cyclic voltametry. Further, it finds use in Diels-Alder reactions. In addition to this, it is used as a paint drier and as an oxygen stripping agent.

The Uses of BIS(CYCLOPENTADIENYL)COBALT

Polymerization inhibitor of olefins up to 200C, Diels–Alder reaction, catalyst, paint drier, oxygen stripping agent.

What are the applications of Application

Bis(cyclopentadienyl)cobalt is a compound also known as Kobaltocen

Definition

A metallocene.

General Description

Black-purple crystals or black solid. Sublimes at 104°F and 0.1 mm Hg.

Air & Water Reactions

Air-sensitive. Highly flammable. Insoluble in water.

Reactivity Profile

BIS(CYCLOPENTADIENYL)COBALT is very sensitive to air and is readily oxidized. BIS(CYCLOPENTADIENYL)COBALT is also sensitive to exposure to light. Readily oxidized by water and dilute acids .

Hazard

Toxic by ingestion.

Health Hazard

ACUTE/CHRONIC HAZARDS: BIS(CYCLOPENTADIENYL)COBALT is toxic by ingestion.

Fire Hazard

Vendor information indicates that BIS(CYCLOPENTADIENYL)COBALT is flammable.

Safety Profile

Poison by intraperitoneal route.Questionable carcinogen with experimental tumorigenicdata. Mutation data reported. When heated todecomposition it emits acrid smoke and fumes.

Properties of BIS(CYCLOPENTADIENYL)COBALT

Melting point: 176-180 °C (dec.)(lit.)
Boiling point: 173℃ [CRC10]
storage temp.  2-8°C
form  crystal
color  purplish-black
Water Solubility  Insoluble in water.
Sensitive  Air & Moisture Sensitive
Stability: Stable, but very reactive and air and moisture sensitive - store under inert gas. Incompatible with strong oxidizing agents. Highly flammable.
CAS DataBase Reference 1277-43-6(CAS DataBase Reference)
EPA Substance Registry System Cobaltocene (1277-43-6)

Safety information for BIS(CYCLOPENTADIENYL)COBALT

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Health Hazard
GHS08
GHS Hazard Statements H228:Flammable solids
H317:Sensitisation, Skin
H334:Sensitisation, respiratory
H341:Germ cell mutagenicity
H351:Carcinogenicity
Precautionary Statement Codes P201:Obtain special instructions before use.
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P308+P313:IF exposed or concerned: Get medical advice/attention.

Computed Descriptors for BIS(CYCLOPENTADIENYL)COBALT

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