BIS(CYCLOPENTADIENYL)COBALT
- CAS NO.:1277-43-6
- Empirical Formula: C10H10Co10*
- Molecular Weight: 189.12
- MDL number: MFCD00013749
- EINECS: 215-061-0
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-15 19:00:21
What is BIS(CYCLOPENTADIENYL)COBALT?
Chemical properties
dark violet crystals
The Uses of BIS(CYCLOPENTADIENYL)COBALT
Bis(cyclopentadienyl)cobalt is used to catalyze the preparation of pyridines from alkynes and nitriles. It acts as a polymerization inhibitor of olefins. It is a common one-electron reducing agent in the laboratory. It reacts with carbon monoxide to prepare cobalt(I) derivative, cyclopentadienylcobalt dicarbonyl. It also serves as an internal standard in cyclic voltametry. Further, it finds use in Diels-Alder reactions. In addition to this, it is used as a paint drier and as an oxygen stripping agent.
The Uses of BIS(CYCLOPENTADIENYL)COBALT
Polymerization inhibitor of olefins up to 200C, Diels–Alder reaction, catalyst, paint drier, oxygen stripping agent.
What are the applications of Application
Bis(cyclopentadienyl)cobalt is a compound also known as Kobaltocen
Definition
A metallocene.
General Description
Black-purple crystals or black solid. Sublimes at 104°F and 0.1 mm Hg.
Air & Water Reactions
Air-sensitive. Highly flammable. Insoluble in water.
Reactivity Profile
BIS(CYCLOPENTADIENYL)COBALT is very sensitive to air and is readily oxidized. BIS(CYCLOPENTADIENYL)COBALT is also sensitive to exposure to light. Readily oxidized by water and dilute acids .
Hazard
Toxic by ingestion.
Health Hazard
ACUTE/CHRONIC HAZARDS: BIS(CYCLOPENTADIENYL)COBALT is toxic by ingestion.
Fire Hazard
Vendor information indicates that BIS(CYCLOPENTADIENYL)COBALT is flammable.
Safety Profile
Poison by intraperitoneal route.Questionable carcinogen with experimental tumorigenicdata. Mutation data reported. When heated todecomposition it emits acrid smoke and fumes.
Properties of BIS(CYCLOPENTADIENYL)COBALT
Melting point: | 176-180 °C (dec.)(lit.) |
Boiling point: | 173℃ [CRC10] |
storage temp. | 2-8°C |
form | crystal |
color | purplish-black |
Water Solubility | Insoluble in water. |
Sensitive | Air & Moisture Sensitive |
Stability: | Stable, but very reactive and air and moisture sensitive - store under inert gas. Incompatible with strong oxidizing agents. Highly flammable. |
CAS DataBase Reference | 1277-43-6(CAS DataBase Reference) |
EPA Substance Registry System | Cobaltocene (1277-43-6) |
Safety information for BIS(CYCLOPENTADIENYL)COBALT
Signal word | Danger |
Pictogram(s) |
Flame Flammables GHS02 Health Hazard GHS08 |
GHS Hazard Statements |
H228:Flammable solids H317:Sensitisation, Skin H334:Sensitisation, respiratory H341:Germ cell mutagenicity H351:Carcinogenicity |
Precautionary Statement Codes |
P201:Obtain special instructions before use. P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P308+P313:IF exposed or concerned: Get medical advice/attention. |
Computed Descriptors for BIS(CYCLOPENTADIENYL)COBALT
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