Benzenesulfonyl hydrazide
Synonym(s):Benzenesulfonylhydrazine;BSH;Porofor BSH
- CAS NO.:80-17-1
- Empirical Formula: C6H8N2O2S
- Molecular Weight: 172.2
- MDL number: MFCD00007583
- EINECS: 201-255-2
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-12-25 13:23:17
What is Benzenesulfonyl hydrazide?
Chemical properties
Benzenesulfonyl hydrazide is WHITE POWDER
Chemical properties
Benzenesulfonohydrazides,unlike the benzenesulfonamides, are thermally unstable. They decompose, when heated in water in some cases, to form sulfides, thiosulfonates, and nitrogen; for this reason they are used as blowing agents in the production of foams.
The Uses of Benzenesulfonyl hydrazide
Benzenesulfonyl hydrazide is used in making foam rubber and foam plastics.
Production Methods
Benzenesulfonyl hydrazides are produced by treating benzenesulfonyl chlorides with hydrazine in dioxane, alcohol, or water and in the presence of a second equivalent of hydrazineoranotherbase. They react with nitrous acid to form benzenesulfonyl azides according to the following equation:
ArSO2NHNH2 +HNO2→RSO2N3 +2H2O
General Description
Benzenesulfonyl hydrazide is a white to light-colored crystalline solid. Insoluble in water and denser than water. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. Readily ignited by sparks or flames and burns vigorously. Used to make other chemicals.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
Self-decomposition or self-ignition may be triggered by heat, chemical reaction, friction or impact. May be ignited by heat, sparks or flames.
Safety Profile
Poison by ingestion. A flammable solid. When heated to decomposition it emits toxic vapors of NOx and SOx.
Properties of Benzenesulfonyl hydrazide
Melting point: | 101-103 °C(lit.) |
Boiling point: | 333.5±25.0 °C(Predicted) |
Density | 1.303 (estimate) |
refractive index | 1.6490 (estimate) |
Flash point: | 110 °C |
storage temp. | Flammables area |
solubility | soluble in Methanol |
form | solid |
pka | 9.30±0.50(Predicted) |
color | White to Almost white |
Merck | 14,7598 |
BRN | 640079 |
CAS DataBase Reference | 80-17-1(CAS DataBase Reference) |
NIST Chemistry Reference | Benzenesulfonic acid, hydrazide(80-17-1) |
EPA Substance Registry System | Benzenesulfonic acid, hydrazide (80-17-1) |
Safety information for Benzenesulfonyl hydrazide
Signal word | Danger |
Pictogram(s) |
Flame Flammables GHS02 Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H242:Self-reactive substances and mixtures; and Organic peroxides H302:Acute toxicity,oral |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P220:Keep/Store away from clothing/…/combustible materials. P234:Keep only in original container. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P280:Wear protective gloves/protective clothing/eye protection/face protection. P420:Store away from other materials. P403+P235:Store in a well-ventilated place. Keep cool. P501:Dispose of contents/container to..… |
Computed Descriptors for Benzenesulfonyl hydrazide
InChIKey | VJRITMATACIYAF-UHFFFAOYSA-N |
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