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HomeProduct name listBenzenesulfonyl hydrazide

Benzenesulfonyl hydrazide

Synonym(s):Benzenesulfonylhydrazine;BSH;Porofor BSH

  • CAS NO.:80-17-1
  • Empirical Formula: C6H8N2O2S
  • Molecular Weight: 172.2
  • MDL number: MFCD00007583
  • EINECS: 201-255-2
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-12-25 13:23:17
Benzenesulfonyl hydrazide Structural

What is Benzenesulfonyl hydrazide?

Chemical properties

Benzenesulfonyl hydrazide is WHITE POWDER

Chemical properties

Benzenesulfonohydrazides,unlike the benzenesulfonamides, are thermally unstable. They decompose, when heated in water in some cases, to form sulfides, thiosulfonates, and nitrogen; for this reason they are used as blowing agents in the production of foams.

The Uses of Benzenesulfonyl hydrazide

Benzenesulfonyl hydrazide is used in making foam rubber and foam plastics.

Production Methods

Benzenesulfonyl hydrazides are produced by treating benzenesulfonyl chlorides with hydrazine in dioxane, alcohol, or water and in the presence of a second equivalent of hydrazineoranotherbase. They react with nitrous acid to form benzenesulfonyl azides according to the following equation:
ArSO2NHNH2 +HNO2→RSO2N3 +2H2O

General Description

Benzenesulfonyl hydrazide is a white to light-colored crystalline solid. Insoluble in water and denser than water. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. Readily ignited by sparks or flames and burns vigorously. Used to make other chemicals.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Self-decomposition or self-ignition may be triggered by heat, chemical reaction, friction or impact. May be ignited by heat, sparks or flames.

Safety Profile

Poison by ingestion. A flammable solid. When heated to decomposition it emits toxic vapors of NOx and SOx.

Properties of Benzenesulfonyl hydrazide

Melting point: 101-103 °C(lit.)
Boiling point: 333.5±25.0 °C(Predicted)
Density  1.303 (estimate)
refractive index  1.6490 (estimate)
Flash point: 110 °C
storage temp.  Flammables area
solubility  soluble in Methanol
form  solid
pka 9.30±0.50(Predicted)
color  White to Almost white
Merck  14,7598
BRN  640079
CAS DataBase Reference 80-17-1(CAS DataBase Reference)
NIST Chemistry Reference Benzenesulfonic acid, hydrazide(80-17-1)
EPA Substance Registry System Benzenesulfonic acid, hydrazide (80-17-1)

Safety information for Benzenesulfonyl hydrazide

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H242:Self-reactive substances and mixtures; and Organic peroxides
H302:Acute toxicity,oral
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P220:Keep/Store away from clothing/…/combustible materials.
P234:Keep only in original container.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P270:Do not eat, drink or smoke when using this product.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P420:Store away from other materials.
P403+P235:Store in a well-ventilated place. Keep cool.
P501:Dispose of contents/container to..…

Computed Descriptors for Benzenesulfonyl hydrazide

InChIKey VJRITMATACIYAF-UHFFFAOYSA-N

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