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HomeProduct name listBenzaldehyde dimethyl acetal

Benzaldehyde dimethyl acetal

Synonym(s):α,α-Dimethoxytoluene;α,α-Dimethoxytoluene

  • CAS NO.:1125-88-8
  • Empirical Formula: C9H12O2
  • Molecular Weight: 152.19
  • MDL number: MFCD00008491
  • EINECS: 214-413-0
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-10-24 21:11:45
Benzaldehyde dimethyl acetal Structural

What is Benzaldehyde dimethyl acetal?

Chemical properties

Clear colorless liquid

Chemical properties

Benzaldehyde dimethyl acetal has a sweet, floral note; also reminiscent of almond

Occurrence

Reported found in rhubarb and potato.

The Uses of Benzaldehyde dimethyl acetal

Benzaldehyde dimethyl acetal used as an effective reagent for the construction of selenocarbonyl compounds.

The Uses of Benzaldehyde dimethyl acetal

Benzaldehyde dimethyl acetal is suitable for use in the synthesis of 4,6-dihydroxy sugar, required for the total synthesis of Porphyromonas gingivalis 381 derived lipid A. It may be used in the preparation of 1-O-methyl-2,3-di-O-galloyl-β-D-glucose.

The Uses of Benzaldehyde dimethyl acetal

Benzaldehyde dimethyl acetal may be used as an analytical reference standard for the quantification of the analyte in fresh and canned fish and Cinnamomum zeylanicum using gas-chromatography coupled to mass spectrometry (GC-MS).

Preparation

From benzaldehyde and methanol in the presence of calcium chloride and HCl; from benzaldehyde and tetramethylorthosilicate in the presence of anhydrous HCl in methanol

Preparation

A mixture of ethylenediamine (1.2 g, 20 mmol), Ph3SbO (1.0 mmol), and P4S10 (2.0 mmol) was autoclaved under a pressure of CO2 (4.9 MPa). Imidazolidinone was isolated by column chromatography (silica gel; eluent: ethyl acetate/hexane, 1:1, v/v); yield 1.5 g (85%).

Definition

ChEBI: (Dimethoxymethyl)benzene is a benzyl ether.

Taste threshold values

Taste characteristics at 25 ppm: green, nutty, brown and sweet

General Description

The abstraction of α-hydrogen atoms from benzaldehyde dimethyl acetal by active bromine at 80°C has been investigated.

Safety Profile

Moderately toxic by ingestion. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.

Properties of Benzaldehyde dimethyl acetal

Melting point: 87-89 C
Boiling point: 87-89 °C/18 mmHg (lit.)
Density  1.014 g/mL at 25 °C (lit.)
refractive index  n20/D 1.493(lit.)
FEMA  2128 | BENZALDEHYDE DIMETHYL ACETAL
Flash point: 157 °F
storage temp.  Inert atmosphere,2-8°C
form  Liquid
color  Clear colorless
Odor at 100.00 %. green earthy rooty nutty vegetable spinach potato fungal almond winey
Water Solubility  decomposes
Sensitive  Moisture Sensitive
JECFA Number 837
BRN  2044501
CAS DataBase Reference 1125-88-8(CAS DataBase Reference)
NIST Chemistry Reference Benzaldehyde dimethyl acetal(1125-88-8)
EPA Substance Registry System Benzene, (dimethoxymethyl)- (1125-88-8)

Safety information for Benzaldehyde dimethyl acetal

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H302:Acute toxicity,oral

Computed Descriptors for Benzaldehyde dimethyl acetal

InChIKey HEVMDQBCAHEHDY-UHFFFAOYSA-N

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