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HomeProduct name listARSENAZO III DISODIUM SALT

ARSENAZO III DISODIUM SALT

  • CAS NO.:62337-00-2
  • Empirical Formula: C22H19As2N4NaO14S2
  • Molecular Weight: 800.36
  • MDL number: MFCD00003936
  • EINECS: 263-516-7
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
ARSENAZO III DISODIUM SALT Structural

What is ARSENAZO III DISODIUM SALT?

Chemical properties

dark brown to brownish-black crystalline powder

The Uses of ARSENAZO III DISODIUM SALT

Arsenazo III disodium salt is a diazo dye reagent used in the spectrophotometric determination of aluminum, gallium and indium. Further, it is used in the complexometric determination of lanthanides, thallium, scandium thorium, uranium and yttrium. In addition to this, it acts as a metal indicator and form specifically colored metal ion complexes in aqueous media.

The Uses of ARSENAZO III DISODIUM SALT

Arsenazo-III is a diazo dye reagent used in the spectrophotometric determination of aluminum, gallium and indium. Toxic if swallowed. Toxic if inhaled. Very toxic to aquatic life.

What are the applications of Application

Arsenazo III disodium salt is a diazo dye reagent used in the spectrophotometric determination of aluminum, gallium and indium

Purification Methods

Contaminants include monoazo derivatives, starting materials for synthesis and by-products. It is partially purified by precipitation of the dye from aqueous alkali on addition of HCl. More thorough purification is achieved by taking a 2g sample in 15-25mL of 5% aqueous NH3 and filter. Add 10mL HCl (1:1) to the filtrate to precipitate the dye. Repeat the procedure and dissolve the solid dye (0.5g) in 7mL of a 1:1:1 mixture of n-propanol/conc NH3/water at 50o. After cooling, filter the solution and chromatograph the filtrate through a cellulose column using a 3:1:1 mixture of n-propanol/conc NH3/water as eluent. Collect the blue band and evaporate it to 10-15mL below 80o, then add 10mL of conc HCl to precipitate pure Arsenazo III. Wash it with EtOH and dry it in air [Borak et al. Talanta 17 215 1970]. The sodium salt is then obtained by dissolving it in the equivalent amount of dilute NaOH and freeze-drying. The purity of the dye can be checked by paper chromatography using M HCl as eluent. It is used for the estimation of Th, U, Zr, Cd and Zn [Michaylova & Yuroukova Anal Chim Acta 68 73 1974.]

Properties of ARSENAZO III DISODIUM SALT

Melting point: >320 °C(lit.)
color  Clear pink
Water Solubility  Soluble in water.

Safety information for ARSENAZO III DISODIUM SALT

Signal word Warning
Pictogram(s)
ghs
Skull and Crossbones
Acute Toxicity
GHS06
ghs
Environment
GHS09
GHS Hazard Statements H301:Acute toxicity,oral
H331:Acute toxicity,inhalation
H400:Hazardous to the aquatic environment, acute hazard
H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P405:Store locked up.

Computed Descriptors for ARSENAZO III DISODIUM SALT

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