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HomeProduct name listALPHA-PHELLANDRENE

ALPHA-PHELLANDRENE

Synonym(s):α-Phellandrene;p-Mentha-1,5-diene;2-Methyl-5-(1-methylethyl)-1,3-cyclohexadiene;5-Isopropyl-2-methyl-1,3-cyclohexadiene;Menthadiene

  • CAS NO.:99-83-2
  • Empirical Formula: C10H16
  • Molecular Weight: 136.23
  • MDL number: MFCD00040419
  • EINECS: 202-792-5
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-07-02 08:55:14
ALPHA-PHELLANDRENE Structural

What is ALPHA-PHELLANDRENE?

Chemical properties

α-Phellandrene has a pleasant, fresh, citrus, peppery odor with a discrete mint note. This compound is also reported as having a minty, herbaceous odor.

Occurrence

The d-form has been reported found in the essential oils of bitter fennel, Ceylon cinnamon leaves, star anise, Curcuma longa and other essential oils; the l-form has been reported found in various eucalyptus oils, orange peel oil, angelica, Lantana camara and other oils. Reported found in over 100 foods and beverages including apricot, many citrus peel oils and juices, black currants, papaya, raspberry, strawberry, carrot, celery leaves and seed, bell pepper, tomato, cinnamon, cumin seed, ginger, Mentha oils, nutmeg, pepper, mace, parsley, thyme, Gruyere cheese, cured pork, hop oil, beer, tea, pecan, passion fruit, sweet and wild marjoram, mango, parsnip, cardamom, coriander seed, gin, litchi, dill herb and seed, lovage leaf and seed, caraway, juniper berry, laurel, bitter and sweet fennel, myrtle leaf and berry, sage, nectarine, pimento leaf and berry and mastic gum leaf oil.

The Uses of ALPHA-PHELLANDRENE

α-Phellandrene is an essential oil component, found to have bactericidal activity.

Definition

ChEBI: One of a pair of phellandrene cyclic monoterpene double-bond isomers in which both double bonds are endocyclic (cf. alpha-phellandrene, where one of them is exocyclic).

Aroma threshold values

Detection: 40 to 200 ppb

Taste threshold values

Taste characteristics at 20 ppm: terpenic, citrus-lime with a fresh green note.

General Description

α-Phellandrene is monoterpene reported to be one of the aroma compounds of black (Piper nigrum) and white ‘‘Ashanti pepper′′ (Piper guineense). It also occurs in the leaves of basil.

Safety Profile

Mdly toxic by ingestion. A severe human skin irritant. Incompatible with air. Flammable liquid when exposed to heat, sparks, or flame. When heated to decomposition it emits acrid smoke and irritating fumes.

Synthesis

The l-form by isolation from Eucalyptus numerosa and similar oils; also from the manufacture of synthetic menthol.

Properties of ALPHA-PHELLANDRENE

Boiling point: 185.55°C (rough estimate)
Density  0.85 g/mL at 25 °C(lit.)
refractive index  n20/D 1.474(lit.)
FEMA  2856 | ALPHA-PHELLANDRENE
Flash point: 117 °F
storage temp.  Store below +30°C.
solubility  Benzene: Soluble; Chloroform: Soluble
form  An oil
Melting point: <25 °C
color  Colorless to light yellow
Odor at 10.00 % in dipropylene glycol. citrus herbal terpene green woody peppery
optical activity [α]20/D 139 to 110°, neat
Merck  13,7277
JECFA Number 1328
Stability: Light Sensitive, Temperature Sensitive
CAS DataBase Reference 99-83-2(CAS DataBase Reference)
EPA Substance Registry System 1,3-Cyclohexadiene, 2-methyl-5-(1-methylethyl)- (99-83-2)

Safety information for ALPHA-PHELLANDRENE

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Health Hazard
GHS08
GHS Hazard Statements H226:Flammable liquids
H304:Aspiration hazard
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

Computed Descriptors for ALPHA-PHELLANDRENE

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