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HomeProduct name listAcryloyl chloride

Acryloyl chloride

Synonym(s):2-Propenoyl chloride;Acrylic acid chloride;Acryloyl chloride

  • CAS NO.:814-68-6
  • Empirical Formula: C3H3ClO
  • Molecular Weight: 90.51
  • MDL number: MFCD00000731
  • EINECS: 212-399-0
  • Update Date: 2024-12-18 14:08:52
Acryloyl chloride Structural

What is Acryloyl chloride?

Chemical properties

Acryloyl chloride is a highly flammable, polymerizable, and toxic (inhalation), light yellow liquid. A lacrimator.

The Uses of Acryloyl chloride

Acryloyl chloride is used in the production of plastics. It plays an important role in the preparation of acrylate monomers and polymers. It also acts as a substrate for cross-metathesis. Further, it is utilized in organic synthesis for the introduction of acrylic groups into other compounds.

Synthesis Reference(s)

Journal of the American Chemical Society, 72, p. 72, 1950 DOI: 10.1021/ja01157a020

General Description

Acryloyl chloride is a liquid. Boiling point 75°C. Used to make plastics. Polymerization in a closed container can cause pressurization and explosive rupture.

Air & Water Reactions

Polymerizes readily upon exposure to oxygen in the air. Reacts exothermically with water to give hydrochloric acid and acrylic acid.

Reactivity Profile

Acrylyl chloride is incompatible with strong oxidizing agents, alcohols, amines, alkali. Polymerizes readily upon exposure to oxygen. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

Fire Hazard

When heated to decomposition, Acrylyl chloride emits toxic fumes of chlorides. Decomposes in water.

Potential Exposure

May be used as a monomer in preparation of specialty polymers or as a chemical intermediate

Shipping

UN3383 Poisonous Toxic by inhalation liquid, flammable, n.o.s. with an LC50 # 200 mL/m3 and saturated vapor concentration ≥500 LC50, Hazard class: 6.1; Labels: 6.1-Poisonous materials, 3-Flammable liquid, Technical Name Required, Inhalation Hazard Zone A. UN2924 Flammable liquids, corrosive, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, 8-Corrosive material, Technical Name Required

Incompatibilities

Use MEHQ (monomethyl ether of hydroquinone) as an inhibitor. Incompatible with oxidizers, polymerizes on contact with oxygen; alcohols, amines, alkalis. Reacts violently with water, releasing hydrochloric acid and acrylic acid. Attacks some metals.

Properties of Acryloyl chloride

Melting point: 76 °C(Solv: isopropyl ether (108-20-3))
Boiling point: 72-76 °C (lit.)
Density  1.114 g/mL at 25 °C (lit.)
vapor density  >1 (vs air)
vapor pressure  1.93 psi ( 20 °C)
refractive index  n20/D 1.435(lit.)
Flash point: 61 °F
storage temp.  2-8°C
solubility  Chloroform (Soluble), Methanol (Slightly)
form  Oil
color  Colourless to Pale Yellow
Water Solubility  Miscible with water.
Sensitive  Moisture & Light Sensitive
BRN  635744
Exposure limits ACGIH: TWA 5 mg/m3 (Skin)
NIOSH: TWA 5 mg/m3
Stability: Stable, but reacts violently with water. Incompatible with alcohols, oxidizing agents, strong bases. Light-sensitive. Highly flammable.
CAS DataBase Reference 814-68-6(CAS DataBase Reference)
NIST Chemistry Reference 2-Propenoyl chloride(814-68-6)
EPA Substance Registry System Acrylyl chloride (814-68-6)

Safety information for Acryloyl chloride

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Corrosion
Corrosives
GHS05
ghs
Skull and Crossbones
Acute Toxicity
GHS06
GHS Hazard Statements H225:Flammable liquids
H290:Corrosive to Metals
H302:Acute toxicity,oral
H314:Skin corrosion/irritation
H330:Acute toxicity,inhalation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Acryloyl chloride

InChIKey HFBMWMNUJJDEQZ-UHFFFAOYSA-N

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