814-68-6
Product Name:
Acryloyl chloride
Formula:
C3H3ClO
Synonyms:
2-Propenoyl chloride;Acrylic acid chloride;Acryloyl chloride
Inquiry
CHEMICAL AND PHYSICAL PROPERTIES
Physical Description | Acrylyl chloride appears as a liquid. Boiling point 75 °C. Used to make plastics. Polymerization in a closed container can cause pressurization and explosive rupture. (EPA, 1998) |
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Color/Form | Liquid |
Boiling Point | 167 °F at 760 mmHg (EPA, 1998) |
Flash Point | 14 °C (57 °F) - closed cup |
Solubility | Soluble in chlorinated solvents |
Density | 1.1136 at 68 °F (EPA, 1998) - Denser than water; will sink |
Vapor Density | 3.63 (Air = 1) |
Vapor Pressure | 93.0 [mmHg] |
Stability/Shelf Life | Stable under recommended storage conditions. Contains the following stabilizer(s): Phenothiazine (400 ppm) |
Decomposition | Hazardous decomposition products formed under fire conditions: Carbon oxides, hydrogen chloride gas. |
Corrosivity | Corrosive to metals |
Polymerization | A 500 mL bottle of the acid chloride stabilized with 0.5% of phenothiazine was shipped to a hot climate without refrigeration, and was stored on arrival in a fume cupboard for 2 days at temperatures approaching 50 °C. The material polymerized, bursting the bottle and forming a solid foam. |
Refractive Index | Index of refraction: 1.4343 at 20 °C/D |
Other Experimental Properties | Hydrolyzed by water |
Chemical Classes | Toxic Gases & Vapors -> Acid Halides |
SAFETY INFORMATION
Signal word | Danger |
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Pictogram(s) |
Flame Flammables GHS02 Corrosion Corrosives GHS05 Skull and Crossbones Acute Toxicity GHS06 |
GHS Hazard Statements |
H225:Flammable liquids H290:Corrosive to Metals H302:Acute toxicity,oral H314:Skin corrosion/irritation H330:Acute toxicity,inhalation |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
COMPUTED DESCRIPTORS
Molecular Weight | 90.51 g/mol |
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XLogP3 | 1.4 |
Hydrogen Bond Donor Count | 0 |
Hydrogen Bond Acceptor Count | 1 |
Rotatable Bond Count | 1 |
Exact Mass | 89.9872424 g/mol |
Monoisotopic Mass | 89.9872424 g/mol |
Topological Polar Surface Area | 17.1 Ų |
Heavy Atom Count | 5 |
Formal Charge | 0 |
Complexity | 57.9 |
Isotope Atom Count | 0 |
Defined Atom Stereocenter Count | 0 |
Undefined Atom Stereocenter Count | 0 |
Defined Bond Stereocenter Count | 0 |
Undefined Bond Stereocenter Count | 0 |
Covalently-Bonded Unit Count | 1 |
Compound Is Canonicalized | Yes |
PRODUCT INTRODUCTION
description
Acrylyl chloride appears as a liquid. Boiling point 75 °C. Used to make plastics. Polymerization in a closed container can cause pressurization and explosive rupture. (EPA, 1998)