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814-68-6

814-68-6 structural image
Product Name: Acryloyl chloride
Formula: C3H3ClO
Synonyms: 2-Propenoyl chloride;Acrylic acid chloride;Acryloyl chloride
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Acrylyl chloride appears as a liquid. Boiling point 75 °C. Used to make plastics. Polymerization in a closed container can cause pressurization and explosive rupture. (EPA, 1998)
Color/Form Liquid
Boiling Point 167 °F at 760 mmHg (EPA, 1998)
Flash Point 14 °C (57 °F) - closed cup
Solubility Soluble in chlorinated solvents
Density 1.1136 at 68 °F (EPA, 1998) - Denser than water; will sink
Vapor Density 3.63 (Air = 1)
Vapor Pressure 93.0 [mmHg]
Stability/Shelf Life Stable under recommended storage conditions. Contains the following stabilizer(s): Phenothiazine (400 ppm)
Decomposition Hazardous decomposition products formed under fire conditions: Carbon oxides, hydrogen chloride gas.
Corrosivity Corrosive to metals
Polymerization A 500 mL bottle of the acid chloride stabilized with 0.5% of phenothiazine was shipped to a hot climate without refrigeration, and was stored on arrival in a fume cupboard for 2 days at temperatures approaching 50 °C. The material polymerized, bursting the bottle and forming a solid foam.
Refractive Index Index of refraction: 1.4343 at 20 °C/D
Other Experimental Properties Hydrolyzed by water
Chemical Classes Toxic Gases & Vapors -> Acid Halides

SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Flame
Flammables
GHS02

Corrosion
Corrosives
GHS05

Skull and Crossbones
Acute Toxicity
GHS06
GHS Hazard Statements H225:Flammable liquids
H290:Corrosive to Metals
H302:Acute toxicity,oral
H314:Skin corrosion/irritation
H330:Acute toxicity,inhalation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

COMPUTED DESCRIPTORS

Molecular Weight 90.51 g/mol
XLogP3 1.4
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 1
Rotatable Bond Count 1
Exact Mass 89.9872424 g/mol
Monoisotopic Mass 89.9872424 g/mol
Topological Polar Surface Area 17.1 Ų
Heavy Atom Count 5
Formal Charge 0
Complexity 57.9
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 1
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Acrylyl chloride appears as a liquid. Boiling point 75 °C. Used to make plastics. Polymerization in a closed container can cause pressurization and explosive rupture. (EPA, 1998)

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