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HomeProduct name listACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)

ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)

Synonym(s):(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I);Acetylacetonato(1,5-cyclooctadiene)rhodium(I);Rh(acac)(COD)

ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Structural

What is ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)?

Chemical properties

Orange crystal

The Uses of ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

General Description

Atomic number of base material: 45 Rhodium

Safety Profile

Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of Rh

Properties of ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)

Melting point: 138-140 °C(lit.)
storage temp.  Inert atmosphere,2-8°C
form  Crystals
color  Yellow to orange
Sensitive  Air Sensitive
Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents
Exposure limits ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3

Safety information for ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
Precautionary Statement Codes P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313:IF SKIN irritation occurs: Get medical advice/attention.
P337+P313:IF eye irritation persists: Get medical advice/attention.

Computed Descriptors for ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)

InChIKey WDIAJTWVVLHUJU-SUESZSCISA-N

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