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HomeProduct name list8-Anilino-1-naphthalenesulfonic acid magnesium salt

8-Anilino-1-naphthalenesulfonic acid magnesium salt

Synonym(s):1,8-ANS magnesium salt;ANSA magnesium salt;Magnesium 8-anilino-1-naphthalenesulfonate hydrate;N-Phenyl peri acid magnesium salt

  • CAS NO.:18108-68-4
  • Empirical Formula: C32H24MgN2O6S2
  • Molecular Weight: 620.98
  • MDL number: MFCD00065353
  • EINECS: 242-004-7
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-01-17 09:39:45
8-Anilino-1-naphthalenesulfonic acid magnesium salt Structural

What is 8-Anilino-1-naphthalenesulfonic acid magnesium salt?

Chemical properties

green crystalline powder

The Uses of 8-Anilino-1-naphthalenesulfonic acid magnesium salt

8-Anilino-1-naphthalenesulfonic Acid Hemimagnesium Salt can be used as catalyst use and in engineered or chemical process of sustainable and scalable synthesis of piperylene sulfone as polymerization inhibitor. Dyes and metabolites.

General Description

ANSA (8-Anilino-1-naphthalenesulfonic acid) is a hydrophobic polarity sensitive fluorescent dye useful as a site probe to detect conformational changes in cell and micelle membranes and molecules such as proteins. ANSA is also used as a fluorescent probe for the estimation of the critical micelle concentration (CMC) of surfactants.

Properties and Applications

GV et al. researched the luminescence of 8-anilino-1-naphthalenesulfonic acid magnesium salt as a hydrophobic probe, which was investigated under the conditions of three-dimensional radical polymerization of methacrylic macromonomers of poly(ethylene oxide) in an aqueous medium. They found that the luminescence intensity rises in the course of gel formation, which is caused by the binding of the probe to hydrophobic polyfunctional branching nodes formed upon the polymerization of terminal methacrylic groups of the macromonomer. Interaction of 8-aniline-1-naphthalenesulfonic acid with a swelled PEO hydrogel also leads to a growth of the luminescence intensity as compared to that in the solution of macromonomers. The addition of NaCl enhances the emission of 8-anilino-1-naphthalenesulfonic acid, probably due to the densification of hydrophobic regions and an increase in the energy of probe binding in these regions[1].

References

[1] Rakova, G. V., and K. S. Kazanskii . "Luminescence of 8-anilino-1-naphthalenesulfonic acid during the formation and swelling of poly(ethylene oxide) hydrogels." Vysokomolekularnye Soedineniya. Ser.A Ser.B Ser.C - Kratkie Soobshcheniya 40.3(1998):501-502.

Properties of 8-Anilino-1-naphthalenesulfonic acid magnesium salt

Melting point: >202°C (dec.)
storage temp.  room temp
solubility  H2O: soluble50mg/mL
form  powder
color  yellow to green
BRN  4834623
Stability: Hygroscopic
InChI InChI=1S/2C16H13NO3S.Mg/c2*18-21(19,20)15-11-5-7-12-6-4-10-14(16(12)15)17-13-8-2-1-3-9-13;/h2*1-11,17H,(H,18,19,20);/q;;+2/p-2
CAS DataBase Reference 18108-68-4(CAS DataBase Reference)
EPA Substance Registry System 1-Naphthalenesulfonic acid, 8-(phenylamino)-, magnesium salt (2:1) (18108-68-4)

Safety information for 8-Anilino-1-naphthalenesulfonic acid magnesium salt

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 8-Anilino-1-naphthalenesulfonic acid magnesium salt

InChIKey IRKGXNAZPUOEMW-UHFFFAOYSA-L
SMILES C12C(=CC=CC=1NC1C=CC=CC=1)C=CC=C2S([O-])(=O)=O.C12C(=CC=CC=1NC1=CC=CC=C1)C=CC=C2S([O-])(=O)=O.[Mg+2]

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