(1R)-(-)-Nopol
Synonym(s):(−)-Nopol;(1R)-6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol;6,6-Dimethyl-2-norpinene-2-ethanol;6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol
- CAS NO.：35836-73-8
- Empirical Formula: C11H18O
- Molecular Weight: 166.26
- MDL number: MFCD00075187
- EINECS: 252-744-2
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-06-07 16:07:22
What is (1R)-(-)-Nopol?
Chemical properties
Clear colorless to light yellow liquid
The Uses of (1R)-(-)-Nopol
(-)-Nopol, is a chiral building block used in chemical synthesis. It is an intermediate that can be used for the synthesis of bulky moiety-modified analogs to the sandalwood odorant Polysantol.
Definition
ChEBI: (-)-Nopol is a monoterpenoid.
What are the applications of Application
(1R)-(-)-Nopol may be used in the preparation of optically active O,O-diterpenyl dithiophosphoric and O-terpenyl aryldithiophosphonic acids by reacting with tetraphosphorus decasulfide and 2,4-diaryl 1,3,2,4-dithiadiphosphetane-2,4-disulfides, respectively. It may also react with silver hexafluoroantimonate to form a complex, which can be an effective initiator for the nonthermal curing of epoxy resins by electron beam induced cationic polymerization.
General Description
(1R)-(-)-Nopol is a chiral terpenol derivative.
Properties of (1R)-(-)-Nopol
| Boiling point: | 235-236 °C(lit.) |
| Density | 0.973 g/mL at 25 °C(lit.) |
| vapor pressure | 2.17Pa at 20℃ |
| refractive index | n |
| Flash point: | 210 °F |
| storage temp. | Refrigerator, under inert atmosphere |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| form | Oil |
| pka | 15.03±0.10(Predicted) |
| color | Clear Colourless |
| optical activity | [α]24/D 37°, neat |
| Water Solubility | 333.5mg/L at 20℃ |
| Merck | 14,6683 |
| BRN | 3196379 |
Safety information for (1R)-(-)-Nopol
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H302:Acute toxicity,oral H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for (1R)-(-)-Nopol
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![6,6-DIMETHYLBICYCLO[3.1.1]HEPT-2-ENE-2-ETHANOL](https://img.chemicalbook.in/CAS/GIF/128-50-7.gif)
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