4,5-DIMETHOXY-2-NITROBENZYL BROMIDE
Synonym(s):6-Nitroveratryl bromide
- CAS NO.:53413-67-5
- Empirical Formula: C9H10BrNO4
- Molecular Weight: 276.08
- MDL number: MFCD00192064
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is 4,5-DIMETHOXY-2-NITROBENZYL BROMIDE?
The Uses of 4,5-DIMETHOXY-2-NITROBENZYL BROMIDE
4,5-Dimethoxy-2-nitrobenzyl bromide (DMNB bromide, 6-nitroveratryl bromide) is suitable reagent used in the synthesis of N-(4,5-dimethoxy-2-nitrobenzyl)vanillylamine which forms caged vanilloid. It may be used in the synthesis of the following:
- 4-(4′,5′-dimethoxy-2-nitrobenzyloxy)benzaldehyde, a DMNB-caged aldehyde
- N-[4-[(4,5-dimethoxy-2-nitrobenzyl)oxy]-3-methoxybenzyl]acetamide
- caged derivative of pyridostatin ([C]-PDS)
- photosensitive polyimide (PI-DMNB)
- caged β-ecdysone
- 4-tert-butyldimethylsilyloxy-1-(2-deoxy-3,5-di-O-toluoyl-β-D-ribofuranosyl)-2-(6-nitroveratrylthio)-1H-benzimidazole, an intermediate in synthesis of phosphoramidite bearing 4-hydroxy-2-mercaptobenzimidazole (SBNV) nucleobase
- alkylation of dihydrofluorescein
- 4-(4′,5′-Dimethoxy-2′-nitrobenzyloxy)benzaldehyde
The Uses of 4,5-DIMETHOXY-2-NITROBENZYL BROMIDE
1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene is a useful research chemical.
General Description
4,5-Dimethoxy-2-nitrobenzyl bromide (DMNBB, 1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene) is a 4,5-dimethoxy-2-nitrobenzyl derivative. 4,5-Dimethoxy-2-nitrobenzyl (DMNB) group of DMNBB is used as a photolabile protecting group in caging technology to develop pro-drugs. Synthesis of 1-(bromomethyl)-4,5-dimethoxy-2-nitrobenzene by using 6-nitroveratraldehyde as starting reagent has been reported.
Properties of 4,5-DIMETHOXY-2-NITROBENZYL BROMIDE
Melting point: | 131-133 °C (lit.) |
Boiling point: | 372.3±37.0 °C(Predicted) |
Density | 1.544 |
storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
form | Crystalline Powder or Needles |
color | Yellow to brown |
Sensitive | Lachrymatory |
Safety information for 4,5-DIMETHOXY-2-NITROBENZYL BROMIDE
Signal word | Danger |
Pictogram(s) |
Corrosion Corrosives GHS05 |
GHS Hazard Statements |
H314:Skin corrosion/irritation |
Precautionary Statement Codes |
P260:Do not breathe dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P363:Wash contaminated clothing before reuse. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 4,5-DIMETHOXY-2-NITROBENZYL BROMIDE
New Products
4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine Nimesulide BP Aceclofenac IP/BP/EP Diclofenac Sodium IP/BP/EP/USP Mefenamic Acid IP/BP/EP/USP Ornidazole IP Diclofenac Potassium SODIUM AAS SOLUTION ZINC AAS SOLUTION BUFFER SOLUTION PH 10.0(BORATE) GOOCH CRUCIBLE SINTERED AQUANIL 5 BERYLLIUM AAS SOLUTION 2-Bromo-1-(bromomethyl)-3-chloro-5-nitrobenzene 2-Bromo-3-nitroaniline N-(3-Hydroxypropyl)-N-methylacetamide 3-Bromo-6-chloropyridazine 4-ethyl-3-nitrobenzoic acidRelated products of tetrahydrofuran
2-(BROMOMETHYL)-4-METHOXY-1-NITROBENZENE
3,4-DIMETHOXYBENZYL BROMIDE
4-(BROMOMETHYL)PHENOL
2-Nitrobenzyl bromide
4-Methoxy-2-nitrobenzyl bromide
4-AMINOCATECHOL HBR
4,5-DIMETHOXY-2-NITROBENZYL BROMIDE
4-Methoxybenzyl bromide
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