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HomeProduct name list4,5-DIMETHOXY-2-NITROBENZYL BROMIDE

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE

Synonym(s):6-Nitroveratryl bromide

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE Structural

What is 4,5-DIMETHOXY-2-NITROBENZYL BROMIDE?

The Uses of 4,5-DIMETHOXY-2-NITROBENZYL BROMIDE

4,5-Dimethoxy-2-nitrobenzyl bromide (DMNB bromide, 6-nitroveratryl bromide) is suitable reagent used in the synthesis of N-(4,5-dimethoxy-2-nitrobenzyl)vanillylamine which forms caged vanilloid. It may be used in the synthesis of the following:

  • 4-(4′,5′-dimethoxy-2-nitrobenzyloxy)benzaldehyde, a DMNB-caged aldehyde
  • N-[4-[(4,5-dimethoxy-2-nitrobenzyl)oxy]-3-methoxybenzyl]acetamide
  • caged derivative of pyridostatin ([C]-PDS)
  • photosensitive polyimide (PI-DMNB)
  • caged β-ecdysone
  • 4-tert-butyldimethylsilyloxy-1-(2-deoxy-3,5-di-O-toluoyl-β-D-ribofuranosyl)-2-(6-nitroveratrylthio)-1H-benzimidazole, an intermediate in synthesis of phosphoramidite bearing 4-hydroxy-2-mercaptobenzimidazole (SBNV) nucleobase
  • alkylation of dihydrofluorescein
  • 4-(4′,5′-Dimethoxy-2′-nitrobenzyloxy)benzaldehyde

The Uses of 4,5-DIMETHOXY-2-NITROBENZYL BROMIDE

1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene is a useful research chemical.

General Description

4,5-Dimethoxy-2-nitrobenzyl bromide (DMNBB, 1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene) is a 4,5-dimethoxy-2-nitrobenzyl derivative. 4,5-Dimethoxy-2-nitrobenzyl (DMNB) group of DMNBB is used as a photolabile protecting group in caging technology to develop pro-drugs. Synthesis of 1-(bromomethyl)-4,5-dimethoxy-2-nitrobenzene by using 6-nitroveratraldehyde as starting reagent has been reported.

Properties of 4,5-DIMETHOXY-2-NITROBENZYL BROMIDE

Melting point: 131-133 °C (lit.)
Boiling point: 372.3±37.0 °C(Predicted)
Density  1.544
storage temp.  under inert gas (nitrogen or Argon) at 2-8°C
form  Crystalline Powder or Needles
color  Yellow to brown
Sensitive  Lachrymatory

Safety information for 4,5-DIMETHOXY-2-NITROBENZYL BROMIDE

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
GHS Hazard Statements H314:Skin corrosion/irritation
Precautionary Statement Codes P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P363:Wash contaminated clothing before reuse.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 4,5-DIMETHOXY-2-NITROBENZYL BROMIDE

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