Contact us: +91 9550333722 040 - 40102781
Structured search
India
Choose your country
Different countries will display different contents
Try our best to find the right business for you.
My chemicalbook

Welcome back!

HomeProduct name list4,4'-Methylene bis(2-chloroaniline)

4,4'-Methylene bis(2-chloroaniline)

Synonym(s):2,2′-Dichloro-4,4′-methylenedianiline;4,4′-Diamino-3,3′-dichlorodiphenylmethane

  • CAS NO.:101-14-4
  • Empirical Formula: C13H12Cl2N2
  • Molecular Weight: 267.15
  • MDL number: MFCD00047829
  • EINECS: 202-918-9
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-07-24 17:31:20
4,4'-Methylene bis(2-chloroaniline) Structural

What is 4,4'-Methylene bis(2-chloroaniline)?

Chemical properties

off-white powder

The Uses of 4,4'-Methylene bis(2-chloroaniline)

MOCA is widely used in machinery, automobile, aircraft manufacturing, mining, industrial and sports facilities (such as plastic track and plastic floor) can be used for curing and waterproof coatings such as epoxy resin, which can be given to polyester and polyether elastomer most good physical and mechanical properties and the results.

The Uses of 4,4'-Methylene bis(2-chloroaniline)

Curing agent for polyurethanes and epoxy resins

What are the applications of Application

4,4′-Methylene-bis(2-chloroaniline) is an analytical standard for aromatic amine determination

Definition

ChEBI: A chloroaniline that consists of two 2-chloroaniline units joined by a methylene bridge.

Production Methods

The production of MOCA in the United States has ceased since 1979 and is now imported, mainly from Japan. More than 1.9 million lb was imported in 1989. The compound is currently used as a curing agent for isocyanate-containing polymers and in the manufacture of polyurethane foams, epoxy resins, gun mounts, jet engine turbine blades, radar systems, and components in home appliances. It is also a model compound for studying carcinogenesis.

General Description

Tan-colored pellets or an off-white solid. Slight odor.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

4,4'-Methylene bis(2-chloroaniline) is a weak base. Undergoes an exothermic and self-sustaining decomposition reaction when exposed to heat above 392°F, In a closed container, the pressure buildup can be rapid enough to cause an explosion.

Hazard

Toxic. A confirmed carcinogen, absorbedby skin. Causes bladder cancer and methe-moglobinemia.

Health Hazard

4,4¢-Methylene bis(2-chloroaniline), or MOCA, is carcinogenic in experimental animals.

Fire Hazard

Flash point data for 4,4'-Methylene bis(2-chloroaniline) are not available. 4,4'-Methylene bis(2-chloroaniline) is probably combustible.

Flammability and Explosibility

Non flammable

Safety Profile

Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Poison by ingestion and intraperitoneal routes. Mutation data reported. Flammable liquid. Reactive with active metals such as sodium, potassium, magnesium, or zinc. When heated to decomposition it emits very toxic fumes of Cland NOx.

Carcinogenicity

4,4′-Methylenebis(2-chloroaniline) is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.

Properties of 4,4'-Methylene bis(2-chloroaniline)

Melting point: 102-107 °C(lit.)
Boiling point: 202-214 °C0.3 mm Hg(lit.)
Density  1.44
vapor pressure  0.001Pa at 20℃
refractive index  1.6710 (estimate)
Flash point: >230 °F
solubility  Acetonitrile (Slightly), DMSO (Slightly), Methanol (Slightly)
form  neat
pka 3.33±0.25(Predicted)
color  Light orange to Yellow to Green
Water Solubility  <0.1 g/100 mL at 25 ºC
Merck  14,6059
BRN  1882318
Stability: Stable, but decomposes exothermically, and possibly explosively, above 200 C. Incompatible with strong oxidizing agents.
CAS DataBase Reference 101-14-4(CAS DataBase Reference)
IARC 1 (Vol. Sup 7, 57, 99, 100F) 2012
NIST Chemistry Reference Aniline), methylene bis-4,4'-(2-chloro-(101-14-4)
EPA Substance Registry System 4,4'-Methylenebis(2-chloroaniline) (101-14-4)

Safety information for 4,4'-Methylene bis(2-chloroaniline)

Signal word Danger
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
ghs
Environment
GHS09
GHS Hazard Statements H302:Acute toxicity,oral
H341:Germ cell mutagenicity
H350:Carcinogenicity
H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P201:Obtain special instructions before use.
P273:Avoid release to the environment.
P308+P313:IF exposed or concerned: Get medical advice/attention.

Computed Descriptors for 4,4'-Methylene bis(2-chloroaniline)

InChIKey IBOFVQJTBBUKMU-UHFFFAOYSA-N

Related products of tetrahydrofuran

You may like

  • 4,4'-Methylenebis(2-chloroaniline) CAS 101-14-4
    4,4'-Methylenebis(2-chloroaniline) CAS 101-14-4
    101-14-4
    View Details
  • 4,4′-Methylene-bis(2-chloroaniline) CAS 101-14-4
    4,4′-Methylene-bis(2-chloroaniline) CAS 101-14-4
    101-14-4
    View Details
  • 7726-95-6 Bromine 99.5% AR (4 x 500ml) 99%
    7726-95-6 Bromine 99.5% AR (4 x 500ml) 99%
    7726-95-6
    View Details
  • Formamide 99%
    Formamide 99%
    75-12-7
    View Details
  • 2, 4-Pyrimidinediamine 3-Oxide 99%
    2, 4-Pyrimidinediamine 3-Oxide 99%
    74638-76-9
    View Details
  • 85-81-4 6-Methoxy-8-Nitroquinoline 99%
    85-81-4 6-Methoxy-8-Nitroquinoline 99%
    85-81-4
    View Details
  • 3-Bromo-4,5-Dihydro-1H-Benzo[B]Azepin-2(3H)-One 99%
    3-Bromo-4,5-Dihydro-1H-Benzo[B]Azepin-2(3H)-One 99%
    86499-96-9
    View Details
  • (−)-Dip-Chloride 85116-37-6 99%
    (−)-Dip-Chloride 85116-37-6 99%
    85116-37-6
    View Details
Statement: All products displayed on this website are only used for non medical purposes such as industrial applications or scientific research, and cannot be used for clinical diagnosis or treatment of humans or animals. They are not medicinal or edible.