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HomeProduct name list4-Methyl-1-pentene

4-Methyl-1-pentene

  • CAS NO.:691-37-2
  • Empirical Formula: C6H12
  • Molecular Weight: 84.16
  • MDL number: MFCD00008949
  • EINECS: 211-720-1
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-12-18 14:15:32
4-Methyl-1-pentene Structural

What is 4-Methyl-1-pentene?

Chemical properties

clear colourless liquid

The Uses of 4-Methyl-1-pentene

4-Methyl-1-pentene is used as a monomer for olefin polymerisation. The resulting polymer is poly(4-methyl-1-pentene). It can also be used to produce 1,2-diiodo-4-methyl-pentane.

The Uses of 4-Methyl-1-pentene

Organic synthesis, monomer for plastics used inautomobiles, electronic components, and laboratoryware.

General Description

Colorless liquid.

Air & Water Reactions

Highly flammable. Water insoluble.

Reactivity Profile

The unsaturated aliphatic hydrocarbons, such as 4-Methyl-1-pentene, are generally much more reactive than the alkanes. Strong oxidizers may react vigorously with them. Reducing agents can react exothermically to release gaseous hydrogen. In the presence of various catalysts (such as acids) or initiators, compounds in this class can undergo very exothermic addition polymerization reactions.

Hazard

Same as for 2-methyl-1-pentene.

Health Hazard

Harmful if inhaled or swallowed. Vapor or mist is irritating to the eyes, mucous membrane and upper respiratory tract. Causes skin irritation. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting.

Fire Hazard

Special Hazards of Combustion Products: Vapors may travel considerable distance to source of ignition and flashback. Container explosion may occur under fire conditions. Forms explosive mixtures in air.

Source

California Phase II reformulated gasoline contained 4-methyl-1-pentene at a concentration of 300 mg/kg (Schauer et al., 2002).

Environmental Fate

Photolytic. Atkinson and Carter (1984) reported a rate constant of 1.06 x 10-16 cm3/molecule?sec for the reaction of 4-methyl-1-pentene in the atmosphere.
Chemical/Physical. Complete combustion in air yields carbon dioxide and water.

Properties of 4-Methyl-1-pentene

Melting point: -155 °C
Boiling point: 53-54 °C(lit.)
Density  0.665 g/mL at 25 °C(lit.)
vapor density  >1 (vs air)
vapor pressure  4.45 psi ( 20 °C)
refractive index  n20/D 1.382(lit.)
Flash point: −25 °F
storage temp.  0-6°C
solubility  Soluble in alcohol, benzene, chloroform, petroleum (Weast, 1986); miscible in pentene, hexane, and heptene.
form  Liquid
color  Colorless
Water Solubility  Soluble in alcohol, benzene, chloroform, petroleum ether. Insoluble in water.
BRN  1731096
Henry's Law Constant 0.615 atm?m3/mol at 25 °C (Hine and Mookerjee, 1975)
CAS DataBase Reference 691-37-2(CAS DataBase Reference)
EPA Substance Registry System 4-Methyl-1-pentene (691-37-2)

Safety information for 4-Methyl-1-pentene

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
GHS Hazard Statements H225:Flammable liquids
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233:Keep container tightly closed.
P240:Ground/bond container and receiving equipment.
P241:Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242:Use only non-sparking tools.
P243:Take precautionary measures against static discharge.

Computed Descriptors for 4-Methyl-1-pentene

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