4-Bromobenzyl alcohol
- CAS NO.：873-75-6
- Empirical Formula: C7H7BrO
- Molecular Weight: 187.03
- MDL number: MFCD00004650
- EINECS: 212-851-7
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is 4-Bromobenzyl alcohol?
Chemical properties
WHITE TO SLIGHTLY BEIGE CRYSTALS OR CRYST. POWDER
The Uses of 4-Bromobenzyl alcohol
4-Bromobenzyl alcohol was used in the synthesis of:
- hydroxyl end functionalized, substituted polyfluorene
- amphiphilic, symmetric rod-coil, triblock copolymer of poly(9,9-didodecylfluorene-2,7-diyl) and poly(hydroxyl ethyl methacrylate)
Synthesis Reference(s)
The Journal of Organic Chemistry, 48, p. 3074, 1983 DOI: 10.1021/jo00166a029
Tetrahedron Letters, 36, p. 3169, 1995 DOI: 10.1016/0040-4039(95)00504-6
General Description
4-Bromobenzyl alcohol undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls. It undergoes oxidation reaction in the presence of polyvinylpolypyrrolidone-supported hydrogen peroxide, silica sulfuric acid and ammonium bromide to yield 4-bromobenzaldehyde. It undergoes efficient trimethylsilylation reaction with 1,1,1,3,3,3-hexamethyldisilazane in the presence of catalytic amount of aspartic acid in acetonitrile.
Flammability and Explosibility
Not classified
Properties of 4-Bromobenzyl alcohol
| Melting point: | 75-77 °C (lit.) |
| Boiling point: | 220.79°C (rough estimate) |
| Density | 1.3839 (rough estimate) |
| vapor pressure | 0.083Pa at 20℃ |
| refractive index | 1.5840 (estimate) |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | dioxane: soluble1g/10 mL, clear to faintly turbid, colorless to faintly yellow |
| pka | 14.16±0.10(Predicted) |
| form | Crystals or Crystalline Powder |
| color | White to slightly beige |
| Water Solubility | 2.31g/L at 20℃ |
| BRN | 1931620 |
| CAS DataBase Reference | 873-75-6(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzenemethanol, 4-bromo-(873-75-6) |
Safety information for 4-Bromobenzyl alcohol
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H412:Hazardous to the aquatic environment, long-term hazard |
| Precautionary Statement Codes |
P273:Avoid release to the environment. P501:Dispose of contents/container to..… |
Computed Descriptors for 4-Bromobenzyl alcohol
| InChIKey | VEDDBHYQWFOITD-UHFFFAOYSA-N |
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product: 873-75-6 4-Bromobenzyl alcohol 98%
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