3,4,9,10-Perylenetetracarboxylic diimide

CAS NO.：81-33-4
Empirical Formula: C24H10N2O4
Molecular Weight: 390.35
MDL number: MFCD00024144
EINECS: 201-344-6
SAFETY DATA SHEET (SDS)
Update Date: 2024-06-04 15:29:52

What is 3,4,9,10-Perylenetetracarboxylic diimide?

Description

Pigment violet 29 is a perylene-based derivative that has a wide range of coloring applications, including paints, inks, paper, carpets, solar cells, and even drugs. Its more formal name is 3,4,9,10-perylenetetracarboxylic acid diimide.
The color of pigment violet 29 has been variously described as dark red-violet, bordeaux, black, maroon, and purple. In its solid form, its color depends on its particle size, its crystallinity, and, in some cases, the angle at which the viewer observes it.
In recent years, the US Environmental Protection Agency reviewed pigment violet 29 under the 2016 update of the Toxic Substances Control Act. In 2018, the EPA reported that the pigment “does not present an unreasonable risk of injury to human health or the environment under the conditions of use.”? The ruling was based on the compound’s low solubility, vapor pressure, and bioaccumulation potential; and, among other factors, its poor absorption across all routes of exposure.
These findings are disputed by Rep. Frank Pallone (D-NJ), who recently became chair of the House Committee on Energy and Commerce. Pallone contends that the EPA did not consider the environmental hazards of the pigment’s uses by individual companies, and he intends to hold hearings on this and other agency rulings.

Chemical properties

Dark yellow red to black solid

The Uses of 3,4,9,10-Perylenetetracarboxylic diimide

Used in chemical research. PTCDI is used extensively as an industrial pigment. It is used as tunable laser dye, light-harvesting material, transistor, molecular switched, solar cell, and optoelectronic device. Planar perylene- and naphthalene-based diimide linkers can be employed to tether the Watson- Crick and the Hoogsteen strands of a DNA triplex, thus providing conjugates capable of targeting singlestranded nucleic acids with the formation of hairpin triplexes.

Definition

ChEBI: The 3,4,9,10-tetracarboxylic diimide derivative of perylene.

Flammability and Explosibility

Not classified

Properties and Applications

TEST ITEMS	SPECIFICATION
APPEARANCE	VIOLET POWDER
SHADE	REDDISH
HEAT RESISTANCE	300 °C min
LIGHT FASTNESS	8
ACID RESISTANCE	5
ALKALI RESISTANCE	5
FASTNESS TO BLEEDING	5
OIL ABSORPTION	40-45%
SPECIFIC SURFACE	28 m ² /g
DENSITY	1.60 g/cm ³
RESIDUE ON 80 MESH	5.0% max
WATER SOLUBLE	1.0% max
VOLATITE 105 °C	1.0% max
TINTING STRENGTH	100-105 %

Properties of 3,4,9,10-Perylenetetracarboxylic diimide

Melting point:	>300 oc
Boiling point:	821.4±61.0 °C(Predicted)
Density	1.680±0.06 g/cm3(Predicted)
storage temp.	Inert atmosphere,Room Temperature
solubility	Sulfuric Acid (Slightly)
form	Powder
appearance	maroon to purple solid
pka	8.75±0.20(Predicted)
color	Purple to Very Dark Purple
Water Solubility	Insoluble in water.
CAS DataBase Reference	81-33-4(CAS DataBase Reference)
EPA Substance Registry System	Anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetrone (81-33-4)

Safety information for 3,4,9,10-Perylenetetracarboxylic diimide

Signal word	Warning
Pictogram(s)	Exclamation Mark Irritant GHS07
GHS Hazard Statements	H302:Acute toxicity,oral H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes	P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.