(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL
Synonym(s):(2S,3R)-(+)-4-Dimethylamino-1,2-diphenyl-3-methyl-2-butanol;(2S,3R)-(+)-4-Dimethylamino-3-methyl-1,2-diphenyl-2-butanol;Dextrocarbinol base
- CAS NO.:38345-66-3
- Empirical Formula: C19H25NO
- Molecular Weight: 283.41
- MDL number: MFCD00066214
- EINECS: 253-893-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-05-04 15:12:56
What is (2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL?
The Uses of (2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL
Reducing reagent in organic synthesis.
Purification Methods
Purify the hydrochloride by dissolving 1.5g in 13.5 mL of 5N HCl, heat to boiling and evaporate in a vacuum. Recrystallise the hydrochloride three times from MeOH/EtOAc giving m 189-190o, []D -33.7o (c 1, H2O) {enantiomer has +34.2o}. The hydrochloride in the minimum volume of water is basified with aqueous 5N NaOH and extracted with Et2O. The extract is dried (K2CO3) and evaporated, leaving a residue which is stored in a desiccator over solid KOH as a low melting solid. It can be recovered using these procedures from asymmetric reductions with LAH, and re-used. [Pohland & Sullivan J Am Chem Soc 77 3400 1955, Sullivan et al. J Org Chem 28 2483 1963, Beilstein 13 IV 2221.]
Properties of (2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL
Melting point: | 54-56 °C(lit.) |
Boiling point: | bp0.1 mm 138-139° |
alpha | 21 +8.2° (c = 10 in ethanol) |
Flash point: | >230 °F |
optical activity | [α]21/D +8.2°, c = 10 in ethanol |
Merck | 13,2070 |
BRN | 2384178 |
EPA Substance Registry System | Benzeneethanol, ?-[(1R)-2-(dimethylamino)-1-methylethyl]-?-phenyl-, (?S)- (38345-66-3) |
Safety information for (2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL
Computed Descriptors for (2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL
New Products
Tubulysin E Tubulysin D Tubulysin I 4-CYANO-TETRAHYDROPYRAN-4-CARBOXYLIC ACID CYCLOBUTYLAMINE HYDROCHLORIDE 4,4-DIFLUOROCYCLOHEXANAMINE 1-(1,1-Difluoroethyl)-2-fluorobenzene 4-(Benzyloxy)-3-bromophenylacetic Acid Methyl (R)-1-Boc-4,4-difluoropyrrolidine-2-carboxylate Calcium Sodium Phosphosilicate IH 2-(1-(Mercaptomethyl) cyclopropyl) acetonitrile Imeglimin Hydrochloride IH 2-[[(3aR,4S,6R,6aS)-6-Aminotetrahydro-2,2-dimethyl-4H-cyclopenta-1,3-dioxol-4-yl]oxy]ethanol ethanedioate 2-[2-[3(S)-3[2-(7-chloro-2-quinolinyl) ethenyl] phenyl-3- hydroxyl propyl] phenyl]-2-propanol Fuel shell Lubiprostone Latanoprostene Bunod Magnesium Trisilicate Flame Retardant Zinc Borate (R)-(3-(3-fluoro-4- thiomorpholinophenyl)-2- oxooxazolidin-4-yl) methyl methanesulfonate methyl 3-fluoro-4- thiomorpholino phenylcarbamate 1H-Imidazole-4-carbonitrile 7-Methoxyquinoline-4-carbonitrile 7-Methoxyquinoline-4-carboxylic acidRelated products of tetrahydrofuran
D-PROPOXYPHENE-D5 HCL (PROPIONYL-D5)
LABOTEST-BB LT00847282
PROPOXYPHENE NAPSYLATE
(2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL
alpha-(+)-4-Dimethylamino-1,2-diphenyl-3-methyl-2-butanol propionate ester
(+/-)-PROPOXYPHENE-D11
PROPOXYPHENE HYDROCHLORIDE
PROPOXYPHENE RELATED COMPOUND A (50 MG) (ALPHA-D-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL HYDROCHLORIDE)
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