2,3,3,4-biphenyl tetracarboxylic dianhydride
- CAS NO.:36978-41-3
- Empirical Formula: C16H6O6
- Molecular Weight: 294.22
- MDL number: MFCD09030654
- EINECS: 811-539-3
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-04 13:44:46
What is 2,3,3,4-biphenyl tetracarboxylic dianhydride?
Description
2,3,3,4-biphenyl tetracarboxylic dianhydride, also known as a-BPDA, is a high-performance polymer with excellent heat resistance, solvent resistance, radiation resistance, and impressive mechanical and dielectric properties. It holds great potential for applications across numerous industries and material fields.
Chemical properties
White to Almost white powder to crystal.
The Uses of 2,3,3,4-biphenyl tetracarboxylic dianhydride
2,3,3',4'-Biphenyltetracarboxylic dianhydride be used for the preparation of a polyimide material.
Preparation
The preparation of 2,3,3',4'-biphenyl tetracarboxylic dianhydride is as follows:In a 1000 ml three-necked flask, 18.3 g (0.1 mol) of 4-chlorophthalic anhydride and 18.3 g (0.1 mol) were added 3-chlorophthalic anhydride, 300 g of anisole as solvent, 0.13 g (0.001 mol) of nickel chloride as a catalyst, 0.198 g (0.001 mol) of C-1 as a catalyst ligand, and 0.03 g (0.0003 mol) of sodium bromide as a catalyst Auxiliary, 13 g (0.2 mol) of zinc powder was used as a reducing agent, and the reaction was stirred at 30 ° C for 8 hours under a nitrogen atmosphere. The reaction solution was filtered to remove insoluble solids in the reaction liquid. 300 g of methanol was added to the filtration mother liquor, and the product was precipitated, filtered, and dried to obtain 25.8 g of the product 2,3,3',4'-biphenyltetracarboxylic dianhydride, yield 87.7%.
What are the applications of Application
2,3,3,4-biphenyl tetracarboxylic dianhydride (a-BPDA) and polyamides (PAA) derived from p-phenylenediamine (PDA) or 4,4'-oxydiphenylamine (ODA) undergo thermal imidisation and can be used for the preparation of asymmetric biphenyl-type polyimides (PI). Compared to the semi-rigid s-BPDA/PDA, the a-BPDA/PDA polyimides have a significantly bent chain structure. However, a-BPDA/PDA films annealed at 350 °C show higher Tg than s-BPDA/PDA films prepared under the same conditions. a-BPDA-based PIs have unexpectedly high Tg values, which may be attributed to the cranked axial motion limiting conformational changes. The diimide synthesised from a-BPDA and cyclohexylamine displays long-lived luminescence of up to 1.3 s after UV irradiation.
Properties of 2,3,3,4-biphenyl tetracarboxylic dianhydride
Melting point: | 199 °C |
Boiling point: | 609.3±48.0 °C(Predicted) |
Density | 1.625±0.06 g/cm3(Predicted) |
storage temp. | Inert atmosphere,Room Temperature |
form | powder to crystal |
color | White to Almost white |
InChI | InChI=1S/C16H6O6/c17-13-9-5-4-7(6-11(9)15(19)21-13)8-2-1-3-10-12(8)16(20)22-14(10)18/h1-6H |
CAS DataBase Reference | 36978-41-3(CAS DataBase Reference) |
EPA Substance Registry System | [4,5'-Biisobenzofuran]-1,1',3,3'-tetrone (36978-41-3) |
Safety information for 2,3,3,4-biphenyl tetracarboxylic dianhydride
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. |
Computed Descriptors for 2,3,3,4-biphenyl tetracarboxylic dianhydride
InChIKey | FYYYKXFEKMGYLZ-UHFFFAOYSA-N |
SMILES | C1(=O)C2=C(C(C3C=CC4C(=O)OC(=O)C=4C=3)=CC=C2)C(=O)O1 |
New Products
SODIUM AAS SOLUTION ZINC AAS SOLUTION BUFFER SOLUTION PH 10.0(BORATE) GOOCH CRUCIBLE SINTERED AQUANIL 5 BERYLLIUM AAS SOLUTION Azithromycin Imp D Azithromycin EP Impurity C Atracurium Besylate EP Impurity D Azithromycin EP Impurity B Azithromycin EP Impurity O Cetirizine Glycerol Ester Impurity HydrochlorideRelated products of tetrahydrofuran
You may like
-
3,4'-Biphthalic Anhydride CAS 36978-41-3View Details
36978-41-3 -
Atracurium Besylate EP Impurity CView Details
86293-35-8 -
Atracurium Besylate EP Impurity DView Details
87046-72-8 -
Azithromycin EP Impurity BView Details
307974-61-4 -
Azithromycin EP Impurity CView Details
620169-47-3 -
Azithromycin EP Impurity OView Details
763924-54-5 -
Azithromycin Imp DView Details
612069-26-8 -
Ceftaroline fosamil Acetate HydrateView Details
400827-55-6