2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
Synonym(s):TMPMgCl·LiCl
- CAS NO.：898838-07-8
- Empirical Formula: C9H18Cl2LiMgN
- Molecular Weight: 242.4
- MDL number: MFCD12546030
- SAFETY DATA SHEET (SDS)
What is 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex?
The Uses of 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex deprotonations using Knochel-Hauser-Base
The Uses of 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
2,2,6,6-Tetramethylpiperidinylmagnesium Chloride Lithium Chloride Complex is used in preparation of Pyridazinones as herbicides. Also, used in preparation of MCL-1 inhibitors useful for treatment of cancer.
The Uses of 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex is a non-nucleophilic Knochel-Hauser base mainly used for the magnesiation of functionalized arenes and heteroarenes to prepare the corresponding Grignard reagents. It can also be used as a base in the synthesis of Π-conjugated polymers via catalyst-transfer polycondensation.
Properties of 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
| Density | 0.96g/mLat 25℃ |
| Flash point: | -15°C |
| storage temp. | 2-8°C |
Safety information for 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
| Signal word | Danger |
| Pictogram(s) |
 Flame Flammables GHS02  Corrosion Corrosives GHS05  Exclamation Mark Irritant GHS07  Health Hazard GHS08 |
| GHS Hazard Statements |
H225:Flammable liquids H302:Acute toxicity,oral H314:Skin corrosion/irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation H351:Carcinogenicity |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P260:Do not breathe dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P370+P378:In case of fire: Use … for extinction. P403+P235:Store in a well-ventilated place. Keep cool. |
Computed Descriptors for 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
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product: 2,2,6,6-Tetramethylpiperidinylmagnesium Chloride Lithium Chloride (Complex 1.0 M in THF) 898838-07-8
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