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HomeProduct name list2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex

Synonym(s):TMPMgCl·LiCl

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Structural

What is 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex?

The Uses of 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex deprotonations using Knochel-Hauser-Base

The Uses of 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex

2,2,6,6-Tetramethylpiperidinylmagnesium Chloride Lithium Chloride Complex is used in preparation of Pyridazinones as herbicides. Also, used in preparation of MCL-1 inhibitors useful for treatment of cancer.

The Uses of 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex is a non-nucleophilic Knochel-Hauser base mainly used for the magnesiation of functionalized arenes and heteroarenes to prepare the corresponding Grignard reagents. It can also be used as a base in the synthesis of Π-conjugated polymers via catalyst-transfer polycondensation.

Properties of 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex

Density  0.96g/mLat 25℃
Flash point: -15°C
storage temp.  2-8°C

Safety information for 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Corrosion
Corrosives
GHS05
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
GHS Hazard Statements H225:Flammable liquids
H302:Acute toxicity,oral
H314:Skin corrosion/irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
H351:Carcinogenicity
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378:In case of fire: Use … for extinction.
P403+P235:Store in a well-ventilated place. Keep cool.

Computed Descriptors for 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex

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