PHENYLMAGNESIUM CHLORIDE
- CAS NO.：100-59-4
- Empirical Formula: C6H5ClMg
- Molecular Weight: 136.86
- MDL number: MFCD00000464
- EINECS: 202-868-8
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-05-04 17:34:30
What is PHENYLMAGNESIUM CHLORIDE?
Chemical properties
yellowish-brown to dark brown solution
The Uses of PHENYLMAGNESIUM CHLORIDE
Phenylmagnesium chloride (PhMgCl) solution is a common Grignard reagent used in the synthesis of (-)-phenserine and stephacidin B. It is employed in a variety of cross-coupling reactions. It can also be used as an electrolyte solution along with aluminium chloride (AlCl3) in the rechargeable magnesium batteries.
The Uses of PHENYLMAGNESIUM CHLORIDE
In organic synthesis, especially in the production of hydrocarbons, alcohols, ketones, organic acids, amines, silicones, boranes.
Definition
ChEBI: Phenylmagnesium chloride is an arylmagnesium halide.
General Description
Phenylmagnesium chloride has been enhanced for energy efficiency. It also used primarily to add an iso-propyl group to carbonyl groups. It can also be used as a strong base in aprotic solvents.
Properties of PHENYLMAGNESIUM CHLORIDE
| Melting point: | 89-90℃ |
| Boiling point: | 230℃ (8 Torr) |
| Density | 0.98 g/mL at 20 °C |
| Flash point: | 1 °F |
| storage temp. | 2-8°C |
| Water Solubility | It reacts violently with water. |
| Sensitive | Air & Moisture Sensitive |
| Merck | 14,7298 |
| BRN | 3587900 |
| CAS DataBase Reference | 100-59-4(CAS DataBase Reference) |
| EPA Substance Registry System | Magnesium, chlorophenyl- (100-59-4) |
Safety information for PHENYLMAGNESIUM CHLORIDE
| Signal word | Danger |
| Pictogram(s) |
 Flame Flammables GHS02  Corrosion Corrosives GHS05  Exclamation Mark Irritant GHS07  Health Hazard GHS08 |
| GHS Hazard Statements |
H225:Flammable liquids H261:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases H302:Acute toxicity,oral H312:Acute toxicity,dermal H314:Skin corrosion/irritation H318:Serious eye damage/eye irritation H333:Acute toxicity,inhalation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation H351:Carcinogenicity H371:Specific target organ toxicity, single exposure H372:Specific target organ toxicity, repeated exposure |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P223:Keep away from any possible contact with water, because of violent reaction and possible flash fire. P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P260:Do not breathe dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P370+P378:In case of fire: Use … for extinction. P405:Store locked up. P403+P233:Store in a well-ventilated place. Keep container tightly closed. P403+P235:Store in a well-ventilated place. Keep cool. P501:Dispose of contents/container to..… |
Computed Descriptors for PHENYLMAGNESIUM CHLORIDE
| InChIKey | GQONLASZRVFGHI-UHFFFAOYSA-M |
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