2-Nitrobiphenyl
- CAS NO.:86-00-0
- Empirical Formula: C12H9NO2
- Molecular Weight: 199.21
- MDL number: MFCD00007126
- EINECS: 201-646-8
- SAFETY DATA SHEET (SDS)
- Update Date: 2025-03-19 18:03:13

What is 2-Nitrobiphenyl?
Chemical properties
CLEAR YELLOW LIQUID AFTER MELTING
The Uses of 2-Nitrobiphenyl
Plasticizer for resins, cellulose acetate and nitrate, polystyrenes; fungicide for textiles; wood preservative; dye intermediate.
Synthesis Reference(s)
Tetrahedron Letters, 36, p. 6567, 1995 DOI: 10.1016/0040-4039(95)01327-E
General Description
Gold to tan crystals or brown solid.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
Aromatic nitro compounds, such as 2-Nitrodiphenyl, range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. The aromatic nitro compounds may explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents. The explosive tendencies of aromatic nitro compounds are increased by the presence of multiple nitro groups.
Fire Hazard
2-Nitrodiphenyl is combustible.
Purification Methods
Crystallise it from EtOH (seeding required). Sublime it under vacuum. [Beilstein 5 H 582, 5 I 273, 5 II 487, 5 III 1750.]
Properties of 2-Nitrobiphenyl
Melting point: | 36-38 °C(lit.) |
Boiling point: | 320 °C |
Density | 1.44 |
vapor density | 5.9 (vs air) |
vapor pressure | 2 mm Hg ( 140 °C) |
refractive index | 1.613-1.615 |
Flash point: | >230 °F |
form | powder to lump |
color | White to Yellow to Green |
Water Solubility | Insoluble |
Merck | 14,6591 |
CAS DataBase Reference | 86-00-0(CAS DataBase Reference) |
NIST Chemistry Reference | 1,1'-Biphenyl, 2-nitro-(86-00-0) |
EPA Substance Registry System | o-Nitrobiphenyl (86-00-0) |
Safety information for 2-Nitrobiphenyl
Signal word | Warning |
Pictogram(s) |
![]() Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 2-Nitrobiphenyl
New Products
3-Iodophenylacetic acid 3-Pyridineacetonitrile, α-hydroxy- 2-Propanamine, 1-chloro-, hydrochloride (9CI) 3-(hexyloxy)-4-(pyridin-3-yl)-1,2,5-thiadiazole 2-Hexyn-1-ol Dibenzo-18-crown-6 Nickel(II) perchlorate hexahydrate, 98% 4-Bromophenylacetonitrile, 95% 3-Bromo-4-fluoroaniline, 97% Sodium tetraborate decahydrate, 98% Palladium(II) acetate, trimer, Pd 99% 4-Bromo-2-chlorotoluene, 97% N N Dimethylformamide Dimethyl Acetal (Dmf Dma) 2,3-Dichloro Benzoyl Cyanide [Side Chain] Bis(2-Chloroethyl) Amine Hydrochloride L-Glutamic Acid Diethyl Ester Hydrochloride 5-(Difluoromethoxy)-2-Mercaptobenzimidazole 1-Ethyl-3-(3-Dimethylaminopropyl)-Carbodiimide Hydrochloride [EDC Hcl] 1,4-Napthoquinone Bromoiodomethane Sodium Bicarbonate Methylene Dichloride (MDC) Ethyl Acetate Indole-3-Carbinol (I3C)Related products of tetrahydrofuran








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