2-METHYL OCTANAL
- CAS NO.:7786-29-0
- Empirical Formula: C9H18O
- Molecular Weight: 142.24
- MDL number: MFCD00216765
- EINECS: 232-093-0
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-06-26 11:39:10
What is 2-METHYL OCTANAL?
Description
2-Methyloctanal has a delicate, floral odor (rose- or lily-like). Prepared by heating methoxymethyl hexyl carbinol with oxalic acid or with anhydrous formic acid; also from hexanal and propionic aldehyde, Darzen’s synthesis of reacting methyl hexyl ketone and ethyl chloroacetate with sodium ethylate; the resulting ester is then hydrolyzed to the acid and this heated under vacuum.
Chemical properties
2-Methyloctanal has a delicate, floral odor, rose- or lily-like
The Uses of 2-METHYL OCTANAL
In effect more versatile than Methyl nonyl acetaldehyde, 2-methyloctanal creates floral-diffusive topnotes in a Lily or Muguet, freshness in Mimosa or Rose, gives clean and airy topnotes to Citrus fragrances, etc. It finds some use in flavor compositions, mainly in Citrus types where it may partly or wholly substitute the conventional Nonanal. Concentration used is about 1 to 2 ppm in the finished product.
Definition
ChEBI: 2-Methyloctanal is a fatty aldehyde.
Safety Profile
Low toxicity by ingestion and skin contact. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
Synthesis
By heating methoxymethyl hexyl carbinol with oxalic acid or with anhydrous formic acid; also from hexanal and propionic aldehyde, Darzen’s synthesis of reacting methyl hexyl ketone and ethyl chloroacetate with sodium ethylate; the resulting ester is then hydrolyzed to the acid and this heated under vacuum.
Properties of 2-METHYL OCTANAL
Melting point: | -18°C (estimate) |
Boiling point: | 189.85°C (estimate) |
Density | 0.8410 |
refractive index | 1.4230 |
FEMA | 2727 | 2-METHYLOCTANAL |
storage temp. | Inert atmosphere,Store in freezer, under -20°C |
solubility | Insoluble in water, soluble in alcohol and oils. |
form | Colourless oily liquid. |
Odor | at 100.00 %. floral rose lily muguet |
JECFA Number | 270 |
EPA Substance Registry System | Octanal, 2-methyl- (7786-29-0) |
Safety information for 2-METHYL OCTANAL
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 2-METHYL OCTANAL
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