4-Nitrotoluene-2-sulfonic Acid
- CAS NO.:121-03-9
- Empirical Formula: C7H7NO5S
- Molecular Weight: 217.2
- MDL number: MFCD00024914
- EINECS: 204-445-3
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-22 13:59:06
What is 4-Nitrotoluene-2-sulfonic Acid?
The Uses of 4-Nitrotoluene-2-sulfonic Acid
5-Nitro-o-toluenesulfonic Acid is a precursor to 4,4''-dinitrostilbene-2,2''-disulfonic acid in fluorescent whitener.
Definition
ChEBI: The arenesulfonic acid that is toluene-2-sulfonic acid bearing a nitro substituent at C-4.
Production Methods
4-Nitrotoluene is sulfonated with 25 % oleum at 60 ℃ and worked up to give a solution of the sodium salt of 2-Methyl-5-nitrobenzenesulfonic acid.
Flammability and Explosibility
Non flammable
4-Nitrotoluene-2-sulfonic acid application
4-Nitrotoluene-2-sulfonic acid is an essential intermediate for producing fluorescent whitening agents, thousands of tons of which are manufactured annually. It is used principally as starting material for the production of 4,4'-dinitrostilbene-2,2'-disulfonic acid, which in turn is used for the manufacture of a host of fluorescent whitening agents based on cyanuric chloride of the 4,4'-bis([1,3,5-triazin-2-yl]amino)-stilbene-2,2'-disulfonic acid type. Further substantial amounts of 4-nitrotoluene-2-sulfonic acid are required to synthesize fluorescent whitening agents with other basic structures and of various dyes.
Properties of 4-Nitrotoluene-2-sulfonic Acid
Melting point: | 135°C |
Boiling point: | 500°C (rough estimate) |
Density | 1.6040 (rough estimate) |
vapor pressure | 0Pa at 20℃ |
refractive index | 1.6100 (estimate) |
storage temp. | Sealed in dry,Room Temperature |
solubility | Methanol (Slightly), Water (Slightly) |
pka | -1.14±0.33(Predicted) |
form | Solid |
color | Very Dark Brown |
Water Solubility | 667g/L at 23℃ |
InChI | InChI=1S/C7H7NO5S/c1-5-2-3-6(8(9)10)4-7(5)14(11,12)13/h2-4H,1H3,(H,11,12,13) |
CAS DataBase Reference | 121-03-9(CAS DataBase Reference) |
EPA Substance Registry System | Benzenesulfonic acid, 2-methyl-5-nitro- (121-03-9) |
Safety information for 4-Nitrotoluene-2-sulfonic Acid
Signal word | Danger |
Pictogram(s) |
Corrosion Corrosives GHS05 |
GHS Hazard Statements |
H290:Corrosive to Metals H314:Skin corrosion/irritation H412:Hazardous to the aquatic environment, long-term hazard |
Precautionary Statement Codes |
P234:Keep only in original container. P260:Do not breathe dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P363:Wash contaminated clothing before reuse. P390:Absorb spillage to prevent material damage. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P405:Store locked up. P406:Store in corrosive resistant/… container with a resistant inner liner. |
Computed Descriptors for 4-Nitrotoluene-2-sulfonic Acid
InChIKey | ZDTXQHVBLWYPHS-UHFFFAOYSA-N |
SMILES | C1(S(O)(=O)=O)=CC([N+]([O-])=O)=CC=C1C |
Abamectin manufacturer
Deepak Nitrite Limited
Aarti Industries Limited (AIL)
Jagson Colorchem Limited
J.J.Nitro Products Pvt. Ltd
DL INTRACHEM
New Products
4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile 4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine Nimesulide BP Aceclofenac IP/BP/EP Mefenamic Acid IP/BP/EP/USP Diclofenac Sodium IP/BP/EP/USP Ornidazole IP Diclofenac Potassium THOMAIND PAPER PH 2.0 TO 4.5 1 BOX BUFFER CAPSULE PH 9.2 - 10 CAP SODIUM CHLORIDE 0.1N CVS ALLOXAN MONOHYDRATE 98% PLATINUM 0.5% ON 3 MM ALUMINA PELLETS (TYPE 73) LITHIUM AAS SOLUTION 2-Bromo-1-(bromomethyl)-3-chloro-5-nitrobenzene 2-Bromo-3-nitroaniline N-(3-Hydroxypropyl)-N-methylacetamide 3-Bromo-6-chloropyridazine 4-ethyl-3-nitrobenzoic acidRelated products of tetrahydrofuran
You may like
-
121-03-9 4-Nitrotoluene-2-sulfonic acid 99%View Details
121-03-9 -
121-03-9 98%View Details
121-03-9 -
121-03-9 4-Nitrotoluene-2-sulfonic acid 98%View Details
121-03-9 -
4-Nitrotoluene-2-sulfonic acid 99%View Details
121-03-9 -
4-Nitrotoluene-2-sulfonic acid 121-03-9 98%View Details
121-03-9 -
121-03-9 98%View Details
121-03-9 -
4-Nitrotoluene-2-sulfonic Acid CAS 121-03-9View Details
121-03-9 -
121-03-9 99%View Details
121-03-9