(2-METHOXY-1-NAPHTHYL)BORONIC ACID
Synonym(s):(2-Methoxy-1-naphthalenyl)boronic acid;(2-Methoxy-1-naphthyl)boronic acid;1-(2-Methoxynaphthyl)boronic acid
- CAS NO.:104116-17-8
- Empirical Formula: C11H11BO3
- Molecular Weight: 202.01
- MDL number: MFCD11044173
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-01-01 23:31:51
What is (2-METHOXY-1-NAPHTHYL)BORONIC ACID?
The Uses of (2-METHOXY-1-NAPHTHYL)BORONIC ACID
Reactant for:
- Design of phosphorus C,P-ligands for environmentally benign cross-coupling reactions
- Sterically hindered Suzuki-Miyaura coupling
- Palladium-catalyzed cross-coupling reactions
- Deboronation homocoupling reactions
- Copper-catalyzed N-arylation of imidazoles
- Stereoselective preparation of biaryl compounds via palladium-catalyzed asymmetric Suzuki-Miyaura coupling
Properties of (2-METHOXY-1-NAPHTHYL)BORONIC ACID
Melting point: | 125-130°C |
Boiling point: | 425.2±47.0 °C(Predicted) |
Density | 1.23±0.1 g/cm3(Predicted) |
storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
pka | 8.53±0.30(Predicted) |
form | solid |
color | White |
InChI | InChI=1S/C11H11BO3/c1-15-10-7-6-8-4-2-3-5-9(8)11(10)12(13)14/h2-7,13-14H,1H3 |
Safety information for (2-METHOXY-1-NAPHTHYL)BORONIC ACID
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for (2-METHOXY-1-NAPHTHYL)BORONIC ACID
InChIKey | NHVWTZOWDLOBBS-UHFFFAOYSA-N |
SMILES | B(C1=C2C(C=CC=C2)=CC=C1OC)(O)O |
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Orthoboric acid
2-(2-Benzyloxynaphthalen-1-yl)-4,4,6-trimethyl-1,3,2-dioxaborinane
2-(2-Benzyloxynaphthalen-1-yl)-5,5-dimethyl-1,3,2-dioxaborinane
2-(2-METHOXY-1-NAPHTHYL)-5,5-DIMETHYL-1,3,2-DIOXABORINANE
2-(2-Methoxynaphthalen-1-yl)-4,4,6-trimethyl-1,3,2-dioxaborinane
(2-METHOXY-1-NAPHTHYL)BORONIC ACID
2-ETHOXY-1-NAPHTHALENEBORONIC ACID
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