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HomeProduct name list2-(Methacryloyloxy)ethyl acetoacetate

2-(Methacryloyloxy)ethyl acetoacetate

Synonym(s):(2-Acetoacetoxy)ethyl methacrylate;AAEM;Ethylene glycol monoacetoacetate monomethacrylate

  • CAS NO.:21282-97-3
  • Empirical Formula: C10H14O5
  • Molecular Weight: 214.22
  • MDL number: MFCD00054405
  • EINECS: 244-311-1
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-08-21 22:41:43
2-(Methacryloyloxy)ethyl acetoacetate  Structural

What is 2-(Methacryloyloxy)ethyl acetoacetate ?

Chemical properties

Clear liquid. Acetoacetoxyethyl Methacrylate [21282- 97-3], AAEM, has a pendant acetoacetoxyethyl group which can modify the physical properties of acrylic polymers by decreasing solution viscosity and lowering the glass transition temperature. In addition, the acetoacetyl group contains an active methylene group and a carbonyl group, which can be used to modify or cross-link the polymer [107].

The Uses of 2-(Methacryloyloxy)ethyl acetoacetate

2-(Methacryloyloxy)ethyl acetoacetate is a methylene active compound that may be used in the synthesis of 2-(methacryloyloxy)ethyl 6-methyl-2-oxo-4-phenyl-1,2,3,4- tetrahydropyrimidine-5-carboxylate. It may be used as a polymerizable chelating agent for metal alkoxides to form polymerizable oxide precursors.

The Uses of 2-(Methacryloyloxy)ethyl acetoacetate

LONZAMON(R) AAEMA is a special methacrylic ester monomer with a reactive methylene group. It is suitable as comonomer for adhesives and coatings as well as copolymer for emulsion polymerisation.

Flammability and Explosibility

Non flammable

Mode of action

The sol-gel polymerization of Si Ti Zr sols is interesting due to the possibility of controlling several properties such as the refractive index, the thermal expansion coefficient, and the resistance against alkaline corrosion attack in the final products (i.e., optical devices, photonics, sensors, and catalysts). The polymerization route can be directed toward the formation of a hybrid organic-inorganic system using a modifying agent such as 2-(methacryloyloxy) ethyl acetoacetate (MEEAH), that can act as a bidentate (bridging or chelating) agent and offers the possibility of being organically polymerizable due to the presence of unsaturated C C bonds in the molecule. The presence of C-C bonds in MEEAH allowed to perform simultaneously the organic and inorganic polymerization while maintaining the homogeneity of the sols and gels. Regarding the partial charge values, in all cases, δ(MEEA?) are negative, indicating that it can easily bond Ti and Zr. On the other hand, δ(OPrn) and δ(OPri ) values are positive in all the molecules where MEEA? is also present, and therefore those species (OPrn and OPri ) are labile[1].

References

[1] J. Méndez-Vivar. “The Role of 2-(Methacryloyloxy) Ethyl Acetoacetate in the Polymerization of Hybrid Multicomponent (Si, Ti, Zr) Sols.” Journal of Sol-Gel Science and Technology 25 3 (2002): 249–254.

Properties of 2-(Methacryloyloxy)ethyl acetoacetate

Melting point: <25 °C
Boiling point: 100 °C/0.8 mmHg (lit.)
Density  1.122 g/mL at 25 °C (lit.)
vapor pressure  0.24Pa at 25℃
refractive index  n20/D 1.456
Flash point: >230 °F
solubility  Insoluble in water
form  clear liquid
pka 10.16±0.46(Predicted)
Specific Gravity 1.122
color  Light yellow to Yellow to Orange
Water Solubility  18.5g/L at 25℃
BRN  2099809
CAS DataBase Reference 21282-97-3(CAS DataBase Reference)
EPA Substance Registry System 2-[Methacryloyloxy]ethyl acetoacetate (21282-97-3)

Safety information for 2-(Methacryloyloxy)ethyl acetoacetate

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H317:Sensitisation, Skin
Precautionary Statement Codes P280:Wear protective gloves/protective clothing/eye protection/face protection.

Computed Descriptors for 2-(Methacryloyloxy)ethyl acetoacetate

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