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HomeProduct name list2-IODO-2-METHYLPROPANE

2-IODO-2-METHYLPROPANE

Synonym(s):tert-Butyl iodide

  • CAS NO.:558-17-8
  • Empirical Formula: C4H9I
  • Molecular Weight: 184.02
  • MDL number: MFCD00001068
  • EINECS: 209-190-1
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-11-28 16:31:44
2-IODO-2-METHYLPROPANE Structural

What is 2-IODO-2-METHYLPROPANE?

Chemical properties

deep brown liquid

The Uses of 2-IODO-2-METHYLPROPANE

2-Iodo-2-methylpropane is used as a chemical reagent in organic synthesis. Further, it serves as a pharmaceutical intermediate.

Synthesis Reference(s)

Tetrahedron Letters, 36, p. 609, 1995 DOI: 10.1016/0040-4039(94)02315-3

General Description

2-Iodo-2-methylpropane was degraded by reductive dehalogenation with nickel-aluminum alloy in potassium hydroxide solution.

Purification Methods

Vacuum distillation has been used to obtain a distillate which remained colourless for several weeks at -5o. More extensive treatment has been used by Boggs, Thompson and Crain [J Phys Chem 61 625 1957] who washed with aqueous NaHSO3 solution to remove free iodine, dried this for 1hour over Na2SO3 at 0o, and purified it by four or five successive partial freezings of the liquid to obtain colourless material and was stored at -78o with Ag wool. [Beilstein 1 IV 300.]

Properties of 2-IODO-2-METHYLPROPANE

Melting point: −38 °C(lit.)
Boiling point: 99-100 °C(lit.)
Density  1.544 g/mL at 25 °C(lit.)
refractive index  n20/D 1.491(lit.)
Flash point: 46 °F
storage temp.  2-8°C
solubility  Miscible with ethanol and ether.
form  clear liquid to cloudy liquid
color  Colorless to Light yellow to Light orange
Sensitive  Light Sensitive
BRN  505950
Dielectric constant 8.4199999999999999
Stability: Stable, but may discolour upon exposure to light. Highly flammable. Incompatible with strong bases, strong oxidizing agents.
CAS DataBase Reference 558-17-8(CAS DataBase Reference)
EPA Substance Registry System Propane, 2-iodo-2-methyl- (558-17-8)

Safety information for 2-IODO-2-METHYLPROPANE

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Exclamation Mark
Irritant
GHS07
ghs
Environment
GHS09
GHS Hazard Statements H225:Flammable liquids
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
H400:Hazardous to the aquatic environment, acute hazard
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233:Keep container tightly closed.
P240:Ground/bond container and receiving equipment.
P273:Avoid release to the environment.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 2-IODO-2-METHYLPROPANE

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