2-Formylbenzenesulfonic acid sodium salt
Synonym(s):2-Sulfobenzaldehyde sodium salt;Benzaldehyde-2-sulfonic acid sodium salt;Sodium 2-formyl-benzolsulfonate
- CAS NO.:1008-72-6
- Empirical Formula: C7H5NaO4S
- Molecular Weight: 208.17
- MDL number: MFCD00007478
- EINECS: 213-758-4
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-04 20:04:50
What is 2-Formylbenzenesulfonic acid sodium salt?
Description
2-Formylbenzenesulfonic acid sodium salt (Sodium o-sulfonate benzaldehyde) is the primary intermediate for synthesizing fluorescent whitening agent CBS, triphenylmethane dye, and moth-repellent N. Fluorescent whitening agent CBS is a new fluorescent whitening agent. It has excellent resistance to chlorine bleaching, acid and alkali resistance, and sunlight resistance. It is an ideal additive for light, textile, and daily chemical industries, mainly used in washing powders, laundry pastes, soaps, toilet soaps, and liquid detergents. Improve the performance of the product, improve the intrinsic quality and appearance quality of the product. Industrially, 2-Formylbenzenesulfonic acid sodium salt is usually obtained by sulfonating sodium sulfite in water with o-chlorobenzaldehyde as the raw material and potassium iodide as the catalyst. The catalyst can be potassium iodide, sodium iodide, and other inorganic substances containing iodide ions.
Chemical properties
white to beige crystalline powder
The Uses of 2-Formylbenzenesulfonic acid sodium salt
2-Formylbenzenesulfonic acid sodium salt was used as precursor to test the ability of fungal strains for transformation of phenolic and non-phenolic precursors into stable and non-toxic dyes.
What are the applications of Application
2-Formylbenzenesulfonic acid sodium salt is used as precursor to test the ability of fungal strains for transformation of phenolic and non-phenolic precursors into stable and non-toxic dyes.
General Description
2-Formylbenzenesulfonic acid sodium salt reacts with chitosan in the presence of sodium cyanoborohydride to yield N-benzyl derivatives.
Purification Methods
It forms prisms or plates by extracting with boiling EtOH, filtering, evaporating to dryness and recrystallising the Na salt from a small volume of H2O. The N-phenylhydrazone sodium salt recrystallises from H2O with m 174.5o. [Gnehm & Schüle Justus Liebigs Ann Chem 299 363 1898, Beilstein 11 IV 652.]
Properties of 2-Formylbenzenesulfonic acid sodium salt
Melting point: | >300°C |
Boiling point: | 562.39℃[at 101 325 Pa] |
vapor pressure | 0Pa at 25℃ |
storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
solubility | H2O: soluble1g/10 mL, clear, colorless to faintly brownish-yellow |
form | Powder |
color | White to pale yellow |
Water Solubility | 1000g/L at 25℃ |
BRN | 4040884 |
Stability: | Stable. Air sensitive. Incompatible with strong oxidizing agents. |
InChI | InChI=1S/C7H6O4S.Na/c8-5-6-3-1-2-4-7(6)12(9,10)11;/h1-5H,(H,9,10,11);/q;+1/p-1 |
CAS DataBase Reference | 1008-72-6(CAS DataBase Reference) |
EPA Substance Registry System | Benzenesulfonic acid, 2-formyl-, sodium salt (1008-72-6) |
Safety information for 2-Formylbenzenesulfonic acid sodium salt
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation |
Precautionary Statement Codes |
P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P332+P313:IF SKIN irritation occurs: Get medical advice/attention. P337+P313:IF eye irritation persists: Get medical advice/attention. |
Computed Descriptors for 2-Formylbenzenesulfonic acid sodium salt
InChIKey | ADPUQRRLAAPXGT-UHFFFAOYSA-M |
SMILES | C1(C=O)C=CC=CC=1S([O-])(=O)=O.[Na+] |
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