2-Chlorophenothiazine
Synonym(s):2-Chlorothiodiphenylamine
- CAS NO.：92-39-7
- Empirical Formula: C12H8ClNS
- Molecular Weight: 233.72
- MDL number: MFCD00005016
- EINECS: 202-152-5
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-19 23:02:33
What is 2-Chlorophenothiazine?
Chemical properties
GREYISH TO SLIGHTLY GREEN OR BROWNISH POWDER
The Uses of 2-Chlorophenothiazine
2-Chlorophenothiazine may be used as starting reagent for the synthesis of N-(10H-phenothiazin-1-yl) benzene sulphonamide.
The Uses of 2-Chlorophenothiazine
Metabolite of Chloropromazine
General Description
2-Chlorophenothiazine is an methylene blue (MB) derivative. Transient resonance Raman and absorption spectra of the lowest excited triplet states T1 and the cation radicals of 2-chlorophenothiazine have been investigated. Molecular semiconductors based on the 1:1 charge-transfer complexes of 2-chlorophenothiazine with 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) have been investigated by X-ray powder diffraction.
Synthesis
(1)2-(3-chloro-phenyl-) benzaminic acid is in the presence of the iron of catalytic amount, in 160～180℃ of following depickling reaction generation m-chloro pentanoic that take place;by step (1) gained m-chloro pentanoic in the presence of the iodine of catalytic amount, at 110～150℃ ring-closure reactions taking place down with sulphur makes described 2-chloro phenothiazine.
Properties of 2-Chlorophenothiazine
| Melting point: | 195-200 °C (lit.) |
| Boiling point: | 395.7±31.0 °C(Predicted) |
| Density | 1.2350 (rough estimate) |
| refractive index | 1.6100 (estimate) |
| storage temp. | 2-8°C |
| solubility | DMSO (Slightly), Methanol (Slightly, Sonicated) |
| form | neat |
| pka | -2.28±0.20(Predicted) |
| color | Pale Beige to Beige |
| BRN | 176587 |
| CAS DataBase Reference | 92-39-7(CAS DataBase Reference) |
| EPA Substance Registry System | 10H-Phenothiazine, 2-chloro- (92-39-7) |
Safety information for 2-Chlorophenothiazine
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H317:Sensitisation, Skin |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P272:Contaminated work clothing should not be allowed out of the workplace. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention. |
Computed Descriptors for 2-Chlorophenothiazine
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Meck Pharmaceuticals and Chemicals Pvt. Ltd.
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Panvo Organics Pvt Ltd
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