2-Bromo-6-methoxypyridine
- CAS NO.：40473-07-2
- Empirical Formula: C6H6BrNO
- Molecular Weight: 188.02
- MDL number: MFCD00088345
- EINECS: 628-883-3
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-06-06 16:20:44
What is 2-Bromo-6-methoxypyridine?
Chemical properties
Light yellow liquid
The Uses of 2-Bromo-6-methoxypyridine
The commercial 2-Bromo-6-methoxypyridine could be used as a starting material to synthesize cyclopenta[b]pyridin-2,5-dione. The overall route consists of a first sequence of regioselective ortho lithiation and methoxycarbonylation followed by Heck vinylation, alkene reduction, cyclization, and decarboxylation[1].
References
[1] Robert, Nicolas , et al. "A convenient synthesis of cyclopenta[b]pyridin-2,5-dione as a non- glycosidic cardiotonic agent." ARKIVOC 2008.7(2008):92-100.
Properties of 2-Bromo-6-methoxypyridine
| Boiling point: | 206 °C (lit.) |
| Density | 1.53 g/mL at 25 °C (lit.) |
| refractive index | n |
| Flash point: | 220 °F |
| storage temp. | Inert atmosphere,Room Temperature |
| form | Liquid |
| pka | -1.04±0.10(Predicted) |
| color | Clear colorless to golden |
| InChI | InChI=1S/C6H6BrNO/c1-9-6-4-2-3-5(7)8-6/h2-4H,1H3 |
| CAS DataBase Reference | 40473-07-2(CAS DataBase Reference) |
Safety information for 2-Bromo-6-methoxypyridine
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 2-Bromo-6-methoxypyridine
| InChIKey | KMODISUYWZPVGV-UHFFFAOYSA-N |
| SMILES | C1(Br)=NC(OC)=CC=C1 |
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product: 2-Bromo-6-methoxy-pyridine 98%
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