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HomeProduct name list2-Benzylaminopyridine

2-Benzylaminopyridine

  • CAS NO.:6935-27-9
  • Empirical Formula: C12H12N2
  • Molecular Weight: 184.24
  • MDL number: MFCD00006251
  • EINECS: 230-060-5
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
2-Benzylaminopyridine Structural

What is 2-Benzylaminopyridine?

Chemical properties

white to off-white powder

The Uses of 2-Benzylaminopyridine

2-(Benzylamino)pyridine is used as a reactant in the amination of aryl chlorides, bromides, and triflates catalyzed by palladium complexes.

Synthesis Reference(s)

Organic Syntheses, Coll. Vol. 4, p. 91, 1963
The Journal of Organic Chemistry, 67, p. 4965, 2002 DOI: 10.1021/jo020057z

General Description

2-Benzylaminopyridine on reaction with BBr3 yields the corresponding amino or hydroxy substituted compounds. It forms 5- and 6-coordinated organometallic complexes of gallium(III) and indium(III).

Properties of 2-Benzylaminopyridine

Melting point: 95-97 °C (lit.)
Boiling point: 116-131 °C/0.6 mmHg (lit.)
Density  1.1160 (rough estimate)
refractive index  1.6266 (estimate)
Flash point: 182°C/12mm
storage temp.  Sealed in dry,2-8°C
form  powder to crystal
pka 6.61±0.10(Predicted)
color  White to Light yellow to Light orange
BRN  134309
CAS DataBase Reference 6935-27-9(CAS DataBase Reference)
EPA Substance Registry System 2-Pyridinamine, N-(phenylmethyl)- (6935-27-9)

Safety information for 2-Benzylaminopyridine

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H302:Acute toxicity,oral
H315:Skin corrosion/irritation
H318:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 2-Benzylaminopyridine

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