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HomeProduct name list2-Amino-1-bromonaphthalene

2-Amino-1-bromonaphthalene

  • CAS NO.:20191-75-7
  • Empirical Formula: C10H8BrN
  • Molecular Weight: 222.08
  • MDL number: MFCD00086888
  • EINECS: 202-080-4
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-08-15 16:24:08
2-Amino-1-bromonaphthalene  Structural

What is 2-Amino-1-bromonaphthalene ?

Chemical properties

White to Light yellow to Light red powder to crystal

Synthesis

The crude naphthalen-2-amine HCl salt (790 mg, 5.5 mmol) and TsOH (170 mg, 1.1 mmol) in THF (50 mL) cooled to 0 0C were treated with NBS (982 mg, 5.5 mmol) in THF (30 mL), and the solution was allowed to warm to 23 0C. After stirring for 5 hours, the reaction mixture was washed with saturated aqueous NaHCO3 (30 mL x 2). The organic layer was dried over anhydrous sodium sulfate and was concentrated to afford 2-Amino-1-bromonaphthalene.
2-AMINO-1-BROMONAPHTHALENE

Properties of 2-Amino-1-bromonaphthalene

Melting point: 63-64 °C(Solv: ligroine (8032-32-4))
Boiling point: 345.5±15.0 °C(Predicted)
Density  1.563±0.06 g/cm3(Predicted)
pka 1.51±0.10(Predicted)

Safety information for 2-Amino-1-bromonaphthalene

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
GHS Hazard Statements H302:Acute toxicity,oral
H312:Acute toxicity,dermal
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H332:Acute toxicity,inhalation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
H351:Carcinogenicity
H412:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P201:Obtain special instructions before use.
P202:Do not handle until all safety precautions have been read and understood.
P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P270:Do not eat, drink or smoke when using this product.
P271:Use only outdoors or in a well-ventilated area.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P330:Rinse mouth.
P362:Take off contaminated clothing and wash before reuse.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313:IF exposed or concerned: Get medical advice/attention.
P332+P313:IF SKIN irritation occurs: Get medical advice/attention.
P337+P313:IF eye irritation persists: Get medical advice/attention.
P405:Store locked up.
P403+P233:Store in a well-ventilated place. Keep container tightly closed.
P501:Dispose of contents/container to..…

Computed Descriptors for 2-Amino-1-bromonaphthalene

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