(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine
- CAS NO.：167316-27-0
- Empirical Formula: C21H22N2O2S
- Molecular Weight: 366.48
- MDL number: MFCD03095684
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine?
Chemical properties
White to slightly yellow crystalline powder
The Uses of (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine
(1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine is used as a catalyst in the synthesis of keramamine C, a carboline alkaloid that is isolated from the Okinawan sponge Amphimedon sp. (1S,2S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine is also used as a catalyst in the synthesis of Tolvaptan (T536650), a selective oral vasopressin V2-receptor agonist that is used to treat hyponatremia.
The Uses of (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine
Chiral diamine ligand for cooperative metal-Bronsted acid catalyzed greener reductive amination using hydrogen gas.
Metal-Br?nsted Acid Cooperative Catalysis for Asymmetric Reductive Amination
General Description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Properties of (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine
| Melting point: | 128-131 °C (lit.) |
| Boiling point: | 537.3±60.0 °C(Predicted) |
| alpha | 61.5 º (C=1, CH2Cl2) |
| Density | 1.1440 (rough estimate) |
| refractive index | 30 ° (C=1, CHCl3) |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| solubility | Solubility in hot Acetonitrile (almost transparency). |
| form | crystal |
| pka | 10.76±0.50(Predicted) |
| color | white |
| optical activity | [α]20/D +35°, c = 1 in chloroform |
| CAS DataBase Reference | 167316-27-0(CAS DataBase Reference) |
Safety information for (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine
Abamectin manufacturer
Evans Fine Chem
1Y
Phone:+91-9821340302
Whatsapp: +91 9821340302
product: 167316-27-0 (S,S)-TsDPEN 99%
New Products
2,2-diethoxyethanethioamide (2S,4R)-4-amino-2-methyl-5-phenylpentanoic acid hydrochloride Tubulysin M Tubulysin D Tubulysin I 2H-Pyran, 4-ethynyltetrahydro- CYCLOBUTYLAMINE HYDROCHLORIDE 2-(azetidin-3-ylidene)acetonitrile (hydrochloride) Isoxazole, 3-[[[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl]methyl]thio]-4,5-dihydro-5,5-dimethyl- 3-N-BOC-(S)-AMINO BUTYRONITRILE 4-(Benzyloxy)-3-bromophenylacetic Acid Imeglimin Hydrochloride IH 2-[[(3aR,4S,6R,6aS)-6-Aminotetrahydro-2,2-dimethyl-4H-cyclopenta-1,3-dioxol-4-yl]oxy]ethanol ethanedioate 2-[2-[3(S)-3[2-(7-chloro-2-quinolinyl) ethenyl] phenyl-3- hydroxyl propyl] phenyl]-2-propanol Calcium Sodium Phosphosilicate IH 2-(1-(Mercaptomethyl) cyclopropyl) acetonitrile Fuel shell Lubiprostone Latanoprostene Bunod Magnesium Trisilicate Flame Retardant Zinc Borate (R)-(3-(3-fluoro-4- thiomorpholinophenyl)-2- oxooxazolidin-4-yl) methyl methanesulfonate methyl 3-fluoro-4- thiomorpholino phenylcarbamate 1H-Imidazole-4-carbonitrileRelated products of tetrahydrofuran
](https://img.chemicalbook.in/StructureFile/ChemBookStructure6/GIF/CB3162860.gif)
![CHLORO[(1S,2S)-N-(P-TOLUENESULFONYL)-1,2-DIPHENYL-1,2-ETHANEDIAMINE] (P-CYMENE)RUTHENIUM(II)](https://img.chemicalbook.in/StructureFile/ChemBookStructure6/GIF/CB9181942.gif)
![CHLORO[(1S,2S)-N-(P-TOLUENESULFONYL)-1,2-DIPHENYL-1,2-ETHANEDIAMINE] (MESITYLENE)RUTHENIUM(II)](https://img.chemicalbook.in/StructureFile/ChemBookStructure6/GIF/CB9204731.gif)
You may like
-
167316-27-0 (S,S)-TsDPEN 99%View Details
167316-27-0 -
167316-27-0 98%View Details
167316-27-0 -
(S,S)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide CAS 167316-27-0View Details
167316-27-0 -
(1S,2S)-(+)-N-p-Tosyl-1,2-diphenylethylenediamine CAS 167316-27-0View Details
167316-27-0 -
(R)-(3-(3-fluoro-4- thiomorpholinophenyl)-2- oxooxazolidin-4-yl) methyl methanesulfonateView Details
2416850-45-6 -
methyl 3-fluoro-4- thiomorpholino phenylcarbamateView Details
2760359-22-4 -
4,6-dichloro-2-propylthiopyrimidine-5-amine 145783-15-9 98%View Details
145783-15-9 -
2-[2-[3(S)-3[2-(7-chloro-2-quinolinyl) ethenyl] phenyl-3- hydroxyl propyl] phenyl]-2-propanol 98%View Details
142569-70-8
Statement: All products displayed on this website are only used for non medical purposes such as industrial applications or scientific research, and cannot be used for clinical diagnosis or treatment of humans or animals. They are not medicinal or edible.