(1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine
Synonym(s):(1R)-trans-N-Boc-1,2-diaminocyclohexane
- CAS NO.：146504-07-6
- Empirical Formula: C11H22N2O2
- Molecular Weight: 214.3
- MDL number: MFCD08726023
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-06-08 17:06:38
What is (1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine?
Chemical properties
White powder
The Uses of (1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine
(1R,2R)-trans-N-Boc-1,2-cyclohexanediamine can be used as:
- An organocatalyst in the intramolecular desymmetrization of cyclohexanones to yield 2-azabicyclo[3.3.1]nonane.
- A starting material in the synthesis of a chiral nickel catalyst applicable for the Michael addition reaction of 1,3-dicarbonyl compounds to yield nitroalkenes.
Definition
ChEBI: (1R,2R)-trans-N-Boc-1,2-cyclohexanediamine is an amine.
Properties of (1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine
| Melting point: | 114-115℃ |
| Boiling point: | 322.1±31.0 °C(Predicted) |
| Density | 1.02±0.1 g/cm3(Predicted) |
| storage temp. | under inert gas (nitrogen or Argon) at 2–8 °C |
| form | powder to crystal |
| pka | 12.26±0.40(Predicted) |
| color | White to Almost white |
| optical activity | [α]/D -26±2°, c = 1 in chloroform |
| BRN | 7023564 |
Safety information for (1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine
| Signal word | Danger |
| Pictogram(s) |
 Corrosion Corrosives GHS05 |
| GHS Hazard Statements |
H314:Skin corrosion/irritation |
| Precautionary Statement Codes |
P260:Do not breathe dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P363:Wash contaminated clothing before reuse. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for (1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine
| InChIKey | AKVIZYGPJIWKOS-RKDXNWHRSA-N |
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