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HomeProduct name list(1R,2R)-(-)-1,2-Diaminocyclohexane

(1R,2R)-(-)-1,2-Diaminocyclohexane

Synonym(s):(1R)-trans-1,2-Cyclohexanediamine

  • CAS NO.:20439-47-8
  • Empirical Formula: C6H14N2
  • Molecular Weight: 114.19
  • MDL number: MFCD00062985
  • EINECS: 606-556-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-11-19 20:33:22
(1R,2R)-(-)-1,2-Diaminocyclohexane Structural

What is (1R,2R)-(-)-1,2-Diaminocyclohexane?

Chemical properties

white to light yellow crystal powder

The Uses of (1R,2R)-(-)-1,2-Diaminocyclohexane

(1R,2R)-(-)-1,2-Diaminocyclohexane can be used as a building block for chiral ligands.

The Uses of (1R,2R)-(-)-1,2-Diaminocyclohexane

suzuki reaction

The Uses of (1R,2R)-(-)-1,2-Diaminocyclohexane

(1R,2R)-(-)-1,2-Diaminocyclohexane is a versatile ligand for the formation of metal complexes. Used in the synthesis of chiral tropocoronands which have potential utility in asymmetric catalysis.

What are the applications of Application

(1R,2R)-(?)-1,2-Diaminocyclohexane is a versatile ligand used for the formation of metal complexes

Purification Methods

Distil or recrystallise the diamine from pet ether under N2 or Ar. Store it as above. The 1R,2R-base L-tartrate salt has M 264.3, m 2 7 3o and [ ] D +12.5o (c 4, H2O), and can be used to purfy and/or optically enrich the free base. [Beilstein 13 III 6, and references below.]

Properties of (1R,2R)-(-)-1,2-Diaminocyclohexane

Melting point: 41-45 °C
Boiling point: 86-88°C 23mm
alpha  -24.5 º (c=5 1 N HCl 20 º 26.5 ºC)
Density  0.931
refractive index  -25.5 ° (C=5, 1mol/L HCl)
Flash point: 169 °F
storage temp.  Keep in dark place,Inert atmosphere,Room temperature
solubility  Aqueous Acid (Slightly), Chloroform (Sparingly), Methanol (Slightly)
form  Crystalline Low Melting Solid
pka 10.76±0.70(Predicted)
color  White to pale yellow
optical activity [α]20/D 25°, c = 5 in 1 M HCl
Water Solubility  Soluble in water.
Sensitive  Air Sensitive
BRN  4780911
Stability: Air Sensitive
CAS DataBase Reference 20439-47-8(CAS DataBase Reference)

Safety information for (1R,2R)-(-)-1,2-Diaminocyclohexane

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
GHS Hazard Statements H314:Skin corrosion/irritation
Precautionary Statement Codes P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P363:Wash contaminated clothing before reuse.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for (1R,2R)-(-)-1,2-Diaminocyclohexane

InChIKey SSJXIUAHEKJCMH-PHDIDXHHSA-N

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