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HomeProduct name list1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE

1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE

Synonym(s):Levoglucosan

  • CAS NO.:498-07-7
  • Empirical Formula: C6H10O5
  • Molecular Weight: 162.14
  • MDL number: MFCD00063248
  • EINECS: 207-855-0
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-12-18 14:07:02
1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE Structural

What is 1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE?

Description

Levoglucosan, a substance formed by heating carbohydrates, has an unusual heterocyclic bicyclo[3.2.1]octane structure. In 1970, C. M. Lakshmann and H. E. Hoelscher reported that it can be produced in large quantities by?pyrolyzing cornstarch under the proper conditions. Levoglucosan is often used as a marker for detecting biomass burning in air quality studies. It is also an?initial product of wood decomposition during forest fires.

Chemical properties

White Crystalline Odourless Solid

The Uses of 1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE

1,6-Anhydro-beta-D-glucopyranose is used for the preparation of biologically important and structurally diverse products such as rifamycin S, indanomycin, thromboxane B2, (+)-biotin, tetrodotoxin, quinone, macrolide antibiotics and modified sugars. It is used as a chemical tracer for biomass burning in atmospheric chemistry studies, particularly with respect to airborne particulate matter. It aids in the production of bioethanol.

The Uses of 1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE

1,6-Anhydrohexopyranoses have proven to be valuable synthons for the preparation of biologically important and structurally diverse products (e.g. rifamycin S, indanomycin, thromboxane B2, (+)-biotin , tetrodotoxin, quinone, and macrolide antibiotics) as well as for modified sugars.

The Uses of 1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE

1,6-Anhydro-β-D-glucose is an useful carbohydrate synthon pharmaceutical intermediate.

What are the applications of Application

1,6-Anhydro-β-D-glucopyranose is a valuable synthon

Definition

ChEBI: A anhydrohexose that is the 1,6-anhydro-derivative of beta-D-glucopyranose.

General Description

1,6-Anhydro-β-D-glucose (Levoglucosa), belonging to the class of anhydrosugars, is an indicator of the burning of biomass in atmospheric aerosol, snow, and ice. It is formed via pyrolysis of glucans, such as cellulose and starch. Levoglucosa is also found in municipal waste and thermochemical processing products of biomass and soil.

Properties of 1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE

Melting point: 182-184 °C(lit.)
Boiling point: 208.81°C (rough estimate)
alpha  -66 º (C=1 IN H2O)
Density  1.2132 (rough estimate)
refractive index  -66.5 ° (C=2, H2O)
storage temp.  2-8°C
solubility  Methanol (Slightly), Water (Sparingly)
pka 13.40±0.60(Predicted)
form  Crystalline Powder or Crystals
color  White to slightly beige
optical activity [α]18/D 66°, c = 1 in H2O
Water Solubility  Soluble in Ethanol and Water.
BRN  80998
Stability: Hygroscopic
NIST Chemistry Reference 1,6-Anhydro-beta-D-glucopyranose(498-07-7)
EPA Substance Registry System .beta.-D-Glucopyranose, 1,6-anhydro- (498-07-7)

Safety information for 1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE

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