1,1'-FERROCENEDICARBOXYLIC ACID
Synonym(s):1,1′-Biscarboxylferrocene;1,1′-Dicarboxyferrocene
- CAS NO.：1293-87-4
- Empirical Formula: C12H10FeO410*
- Molecular Weight: 274.05
- MDL number: MFCD00001423
- EINECS: 215-068-9
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-09-02 13:12:44
What is 1,1'-FERROCENEDICARBOXYLIC ACID?
Chemical properties
dark brown powder
The Uses of 1,1'-FERROCENEDICARBOXYLIC ACID
Reactant for preparation of:
- Planar chiral ferrocene-based amido-phosphine ligands as catalysts for asymmetric allylic alkylation reactions
- Potential antitumor agents
- Isostructural ferrocenyl coordination polymer hollow microspheres with H2 storage properties
- Prganometallic aromatic polyesters
- Manganese-lanthanide-ferrocene clusters
What are the applications of Application
1,1′-Ferrocenedicarboxylic acid is Reactant for preparation of planar chiral ferrocene-based amido-phosphine ligands
Purification Methods
It crystallises in orange-yellow crystals from AcOH and sublimes above 230o. The monomethyl ester has m 147-149o [Nesmeyanov & Reutov Dokl Acad Nauk USSS 115 518 1957]. The dimethyl ester has m 114-115o [Woodward et al. J Am Chem Soc 74, 3458 1953]. The diacid chloride has m 92-93o when recrystallised from pet ether. [Nesmeyanov & Reutov Dokl Acad Nauk SSSR 120 1267 1958, Kazitsyna et al. Dokl Acad Nauk SSSR 127 333 1959, Beilstein 16 IV 1811.]
Properties of 1,1'-FERROCENEDICARBOXYLIC ACID
| Melting point: | ≥300 °C(lit.) |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | DMSO, Ethyl Acetate (Very Slightly, Heated, Sonicated) |
| form | crystal |
| color | orange |
| Water Solubility | Insoluble |
| Exposure limits | ACGIH: TWA 1 mg/m3 NIOSH: TWA 1 mg/m3 |
| Stability: | Stable. Incompatible with strong oxidizing agents. |
| CAS DataBase Reference | 1293-87-4 |
| NIST Chemistry Reference | 1,1'-Ferrocenedicarboxylic acid(1293-87-4) |
Safety information for 1,1'-FERROCENEDICARBOXYLIC ACID
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 1,1'-FERROCENEDICARBOXYLIC ACID
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![1,1''-([4,4'-BIPIPERIDINE]-1,1'-DIYLDICARBONYL)BIS[1'-(METHOXYCARBONYL) FERROCENE]](https://img.chemicalbook.in/CAS/GIF/130882-76-7.gif)
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