1,1'-FERROCENEDICARBOXYLIC ACID
Synonym(s):1,1′-Biscarboxylferrocene;1,1′-Dicarboxyferrocene
- CAS NO.：1293-87-4
- Empirical Formula: C12H10FeO410*
- Molecular Weight: 274.05
- MDL number: MFCD00001423
- EINECS: 215-068-9
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-09-02 13:12:44
What is 1,1'-FERROCENEDICARBOXYLIC ACID?
Chemical properties
dark brown powder
The Uses of 1,1'-FERROCENEDICARBOXYLIC ACID
Reactant for preparation of:
- Planar chiral ferrocene-based amido-phosphine ligands as catalysts for asymmetric allylic alkylation reactions
- Potential antitumor agents
- Isostructural ferrocenyl coordination polymer hollow microspheres with H2 storage properties
- Prganometallic aromatic polyesters
- Manganese-lanthanide-ferrocene clusters
What are the applications of Application
1,1′-Ferrocenedicarboxylic acid is Reactant for preparation of planar chiral ferrocene-based amido-phosphine ligands
Purification Methods
It crystallises in orange-yellow crystals from AcOH and sublimes above 230o. The monomethyl ester has m 147-149o [Nesmeyanov & Reutov Dokl Acad Nauk USSS 115 518 1957]. The dimethyl ester has m 114-115o [Woodward et al. J Am Chem Soc 74, 3458 1953]. The diacid chloride has m 92-93o when recrystallised from pet ether. [Nesmeyanov & Reutov Dokl Acad Nauk SSSR 120 1267 1958, Kazitsyna et al. Dokl Acad Nauk SSSR 127 333 1959, Beilstein 16 IV 1811.]
Properties of 1,1'-FERROCENEDICARBOXYLIC ACID
| Melting point: | ≥300 °C(lit.) |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | DMSO, Ethyl Acetate (Very Slightly, Heated, Sonicated) |
| form | crystal |
| color | orange |
| Water Solubility | Insoluble |
| Exposure limits | ACGIH: TWA 1 mg/m3 NIOSH: TWA 1 mg/m3 |
| Stability: | Stable. Incompatible with strong oxidizing agents. |
| CAS DataBase Reference | 1293-87-4 |
| NIST Chemistry Reference | 1,1'-Ferrocenedicarboxylic acid(1293-87-4) |
Safety information for 1,1'-FERROCENEDICARBOXYLIC ACID
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 1,1'-FERROCENEDICARBOXYLIC ACID
New Products
4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile 4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine Nimesulide BP Aceclofenac IP/BP/EP Diclofenac Sodium IP/BP/EP/USP Mefenamic Acid IP/BP/EP/USP Ornidazole IP Diclofenac Potassium THOMAIND PAPER PH 2.0 TO 4.5 1 BOX BUFFER CAPSULE PH 9.2 - 10 CAP SODIUM CHLORIDE 0.1N CVS ALLOXAN MONOHYDRATE 98% PLATINUM 0.5% ON 3 MM ALUMINA PELLETS (TYPE 73) LITHIUM AAS SOLUTION 2-Bromo-1-(bromomethyl)-3-chloro-5-nitrobenzene 2-Bromo-3-nitroaniline N-(3-Hydroxypropyl)-N-methylacetamide 3-Bromo-6-chloropyridazine 4-ethyl-3-nitrobenzoic acidRelated products of tetrahydrofuran
![1,1''-([4,4'-BIPIPERIDINE]-1,1'-DIYLDICARBONYL)BIS[1'-(METHOXYCARBONYL) FERROCENE]](https://img.chemicalbook.in/CAS/GIF/130882-76-7.gif)
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