Ferrocenecarboxaldehyde
Synonym(s):Cyclopentadienyl(formylcyclopentadienyl)iron
- CAS NO.：12093-10-6
- Empirical Formula: C11H10FeO10*
- Molecular Weight: 214.04
- MDL number: MFCD00001429
- EINECS: 235-158-1
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-11-09 17:14:14
What is Ferrocenecarboxaldehyde?
Chemical properties
crystalline solid
The Uses of Ferrocenecarboxaldehyde
Ferrocenecarboxaldehyde, is used to prepare chiral ferrocene aziridinylmethanols for selective azomethine ylide cycloaddtion. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals.
What are the applications of Application
Ferrocenecarboxaldehyde is used to prepare chiral ferrocene aziridinylmethanols for selective azomethine ylide cycloaddtion
Purification Methods
It forms red crystals from heptane/CH2Cl2, EtOH or pet ether and sublimes at 70o/1mm. The cyanohydrin has m 104o (from *C6H6/EtOH). The semicarbazone has m 217-219o(dec) after recrystallisation from aqueous EtOH. The oxime provides two isomers from pet ether viz m 96-99o and m 155o. The O-acetyloxime has m 80-81o after recrystallisation from hexane [Lindsay & Hauser J Org Chem 22 355 1957]. The 2,4-dinitrophenylhydrazone has m 248o(dec). [Beilstein 16 IV 1798, Graham et al. J Am Chem Soc 79 3416 1957, Broadhead et al. J Chem Soc 650 1958.]
Properties of Ferrocenecarboxaldehyde
| Melting point: | 118-120 °C (lit.) |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| form | Crystalline Powder or Crystals or Crystals |
| color | Orange to red to brown |
| Water Solubility | INSOLUBLE |
| Sensitive | Air Sensitive |
| λmax | 314nm(DMF aq.)(lit.) |
| Exposure limits | ACGIH: TWA 1 mg/m3 NIOSH: TWA 1 mg/m3 |
| Stability: | Stable. Incompatible with strong oxidizing agents. |
| EPA Substance Registry System | Ferrocenecarboxaldehyde (12093-10-6) |
Safety information for Ferrocenecarboxaldehyde
Computed Descriptors for Ferrocenecarboxaldehyde
New Products
Tubulysin H Tubulysin E (2S,4R)-4-amino-2-methyl-5-phenylpentanoic acid hydrochloride Methyl (R)-1-Boc-4,4-difluoropyrrolidine-2-carboxylate Isoxazole, 3-[[[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl]methyl]thio]-4,5-dihydro-5,5-dimethyl- 4,4-DIFLUOROPIPERIDINE 4,4-DIFLUOROCYCLOHEXANAMINE 2H-Pyran, 4-ethynyltetrahydro- CYCLOBUTYLAMINE HYDROCHLORIDE Calcium Sodium Phosphosilicate IH Imeglimin Hydrochloride IH 2-[2-[3(S)-3[2-(7-chloro-2-quinolinyl) ethenyl] phenyl-3- hydroxyl propyl] phenyl]-2-propanol Fuel shell 2-[[(3aR,4S,6R,6aS)-6-Aminotetrahydro-2,2-dimethyl-4H-cyclopenta-1,3-dioxol-4-yl]oxy]ethanol ethanedioate 2-(1-(Mercaptomethyl) cyclopropyl) acetonitrile Lubiprostone Latanoprostene Bunod Magnesium Trisilicate Flame Retardant Zinc Borate (R)-(3-(3-fluoro-4- thiomorpholinophenyl)-2- oxooxazolidin-4-yl) methyl methanesulfonate methyl 3-fluoro-4- thiomorpholino phenylcarbamate 1H-Imidazole-4-carbonitrile 7-Methoxyquinoline-4-carboxylic acid 7-Methoxyquinoline-4-carbonitrileRelated products of tetrahydrofuran
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