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HomeProduct name listFerrocenecarboxaldehyde

Ferrocenecarboxaldehyde

Synonym(s):Cyclopentadienyl(formylcyclopentadienyl)iron

  • CAS NO.:12093-10-6
  • Empirical Formula: C11H10FeO10*
  • Molecular Weight: 214.04
  • MDL number: MFCD00001429
  • EINECS: 235-158-1
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-11-09 17:14:14
Ferrocenecarboxaldehyde Structural

What is Ferrocenecarboxaldehyde?

Chemical properties

crystalline solid

The Uses of Ferrocenecarboxaldehyde

Ferrocenecarboxaldehyde, is used to prepare chiral ferrocene aziridinylmethanols for selective azomethine ylide cycloaddtion. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals.

What are the applications of Application

Ferrocenecarboxaldehyde is used to prepare chiral ferrocene aziridinylmethanols for selective azomethine ylide cycloaddtion

Purification Methods

It forms red crystals from heptane/CH2Cl2, EtOH or pet ether and sublimes at 70o/1mm. The cyanohydrin has m 104o (from *C6H6/EtOH). The semicarbazone has m 217-219o(dec) after recrystallisation from aqueous EtOH. The oxime provides two isomers from pet ether viz m 96-99o and m 155o. The O-acetyloxime has m 80-81o after recrystallisation from hexane [Lindsay & Hauser J Org Chem 22 355 1957]. The 2,4-dinitrophenylhydrazone has m 248o(dec). [Beilstein 16 IV 1798, Graham et al. J Am Chem Soc 79 3416 1957, Broadhead et al. J Chem Soc 650 1958.]

Properties of Ferrocenecarboxaldehyde

Melting point: 118-120 °C (lit.)
storage temp.  Keep in dark place,Sealed in dry,Room Temperature
form  Crystalline Powder or Crystals or Crystals
color  Orange to red to brown
Water Solubility  INSOLUBLE
Sensitive  Air Sensitive
λmax 314nm(DMF aq.)(lit.)
Exposure limits ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3
Stability: Stable. Incompatible with strong oxidizing agents.
EPA Substance Registry System Ferrocenecarboxaldehyde (12093-10-6)

Safety information for Ferrocenecarboxaldehyde

Computed Descriptors for Ferrocenecarboxaldehyde

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