Ferrocenecarboxaldehyde
Synonym(s):Cyclopentadienyl(formylcyclopentadienyl)iron
- CAS NO.:12093-10-6
- Empirical Formula: C11H10FeO10*
- Molecular Weight: 214.04
- MDL number: MFCD00001429
- EINECS: 235-158-1
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-11-09 17:14:14
What is Ferrocenecarboxaldehyde?
Chemical properties
crystalline solid
The Uses of Ferrocenecarboxaldehyde
Ferrocenecarboxaldehyde, is used to prepare chiral ferrocene aziridinylmethanols for selective azomethine ylide cycloaddtion. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals.
What are the applications of Application
Ferrocenecarboxaldehyde is used to prepare chiral ferrocene aziridinylmethanols for selective azomethine ylide cycloaddtion
Purification Methods
It forms red crystals from heptane/CH2Cl2, EtOH or pet ether and sublimes at 70o/1mm. The cyanohydrin has m 104o (from *C6H6/EtOH). The semicarbazone has m 217-219o(dec) after recrystallisation from aqueous EtOH. The oxime provides two isomers from pet ether viz m 96-99o and m 155o. The O-acetyloxime has m 80-81o after recrystallisation from hexane [Lindsay & Hauser J Org Chem 22 355 1957]. The 2,4-dinitrophenylhydrazone has m 248o(dec). [Beilstein 16 IV 1798, Graham et al. J Am Chem Soc 79 3416 1957, Broadhead et al. J Chem Soc 650 1958.]
Properties of Ferrocenecarboxaldehyde
Melting point: | 118-120 °C (lit.) |
storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
form | Crystalline Powder or Crystals or Crystals |
color | Orange to red to brown |
Water Solubility | INSOLUBLE |
Sensitive | Air Sensitive |
λmax | 314nm(DMF aq.)(lit.) |
Exposure limits | ACGIH: TWA 1 mg/m3 NIOSH: TWA 1 mg/m3 |
Stability: | Stable. Incompatible with strong oxidizing agents. |
EPA Substance Registry System | Ferrocenecarboxaldehyde (12093-10-6) |
Safety information for Ferrocenecarboxaldehyde
Computed Descriptors for Ferrocenecarboxaldehyde
New Products
4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine Nimesulide BP Aceclofenac IP/BP/EP Diclofenac Sodium IP/BP/EP/USP Mefenamic Acid IP/BP/EP/USP Ornidazole IP Diclofenac Potassium SODIUM AAS SOLUTION ZINC AAS SOLUTION BUFFER SOLUTION PH 10.0(BORATE) GOOCH CRUCIBLE SINTERED AQUANIL 5 BERYLLIUM AAS SOLUTION 2-Bromo-1-(bromomethyl)-3-chloro-5-nitrobenzene 2-Bromo-3-nitroaniline N-(3-Hydroxypropyl)-N-methylacetamide 3-Bromo-6-chloropyridazine 4-ethyl-3-nitrobenzoic acidRelated products of tetrahydrofuran
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