1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,
Synonym(s):PdCl2(dtbpf)
- CAS NO.:95408-45-0
- Empirical Formula: C26H38Cl2FeP2Pd
- Molecular Weight: 645.7
- MDL number: MFCD08064219
- EINECS: 664-483-5
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-03-18 16:05:00
What is 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, ?
Chemical properties
reddish brown crystal
The Uses of 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,
suzuki reaction
The Uses of 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,
1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride is used as a catalyst for the preparation of chalcones.
The Uses of 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,
Coupling reactions, Suzuki couplings.Dichloro[1,1'-bis(di-tert-butylphosphino)ferrocene] palladium(II) is used as a catalyst in Suzuki-cross coupling reactions, which involve reaction of aromatic halides with methyliminodiacetic acid derivatives. it is also used as a catalyst for the preparation of chalcones. It is used in the preparation of (bisphosphinometallocene)-palladium(II) chloride complexes, which used as a starting material for the Buchwald-Hartwig reaction.
What are the applications of Application
1,1′-Bis(di-tert-butylphosphino)ferrocene palladium dichloride is a catalyst for cross-coupling reactions
General Description
This product has been enhanced for catalytic efficiency.
Properties of 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,
Melting point: | 203-208 °C |
storage temp. | -20°C |
solubility | Soluble in dichloromethane and chloroform. Partially soluble in acetone, alcohols, tertrahydrofuran and dioxane. |
form | crystal |
color | dark purple |
InChI | InChI=1S/2C13H19P.2ClH.Fe.Pd/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;;;;/h2*14H,1-6H3;2*1H;;/q;;;;+2;/p-2 |
CAS DataBase Reference | 95408-45-0 |
Safety information for 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,
InChIKey | ORDFDLUOXDTTTD-UHFFFAOYSA-L |
SMILES | C(P1([Pd+2](P(C(C)(C)C)(C(C)(C)C)[C-]23C4=C5C6=C2[Fe+2]27893456C3C2=C7[C-]18C9=3)([Cl-])[Cl-])C(C)(C)C)(C)(C)C |
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