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HomeProduct name list1-Naphthyl isocyanate

1-Naphthyl isocyanate

  • CAS NO.:86-84-0
  • Empirical Formula: C11H7NO
  • Molecular Weight: 169.18
  • MDL number: MFCD00003814
  • EINECS: 201-703-7
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-12-18 14:15:30
1-Naphthyl isocyanate Structural

What is 1-Naphthyl isocyanate?

Chemical properties

colourless or slightly yellow liquid

The Uses of 1-Naphthyl isocyanate

1-Naphthyl isocyanate is used in the preparation of cationic aromatic urethane. It is useful for the study of cholangiolitic hepatotoxicity in laboratory animals. It is also employed as separate enantiomers of beta-blockers.

Synthesis Reference(s)

Synthetic Communications, 23, p. 335, 1993 DOI: 10.1080/00397919308009785

Purification Methods

Distil the isocyanate at atmospheric pressure or in a vacuum. It can be crystallised from pet ether (b 60-70o) at low temperature. It has a pungent odour, is TOXIC and is absorbed through the skin. [Beilstein 12 H 1244, 12 III 2948.]

Properties of 1-Naphthyl isocyanate

Melting point: 4 °C (lit.)
Boiling point: 267 °C/761 mmHg (lit.)
Density  1.177 g/mL at 25 °C (lit.)
vapor density  2.9 (vs air)
vapor pressure  168.8 mm Hg ( 37.7 °C)
refractive index  n20/D 1.6344(lit.)
Flash point: -1 °F
storage temp.  Inert atmosphere,2-8°C
solubility  Miscible with alcohol, chloroform and diethyl ether.
form  clear liquid
color  Colorless to Light yellow to Light orange
Sensitive  Moisture Sensitive
Merck  14,6410
BRN  742779
Stability: Stable. Incompatible with strong oxidizing agents, alcohols.
CAS DataBase Reference 86-84-0(CAS DataBase Reference)
NIST Chemistry Reference Naphthalene, 1-isocyanato-(86-84-0)
EPA Substance Registry System 1-Isocyanatonaphthalene (86-84-0)

Safety information for 1-Naphthyl isocyanate

Signal word Danger
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
GHS Hazard Statements H315:Skin corrosion/irritation
H317:Sensitisation, Skin
H319:Serious eye damage/eye irritation
H334:Sensitisation, respiratory
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 1-Naphthyl isocyanate

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