1-Bromo-4-(trifluoromethoxy)benzene
Synonym(s):1-Bromo-4-(trifluoromethoxy)benzene;p-Trifluoromethoxy bromo benzene
- CAS NO.：407-14-7
- Empirical Formula: C7H4BrF3O
- Molecular Weight: 241.01
- MDL number: MFCD00040834
- EINECS: 206-979-2
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-21 22:41:43
What is 1-Bromo-4-(trifluoromethoxy)benzene?
Chemical properties
CLEAR COLOURLESS TO YELLOW LIQUID
The Uses of 1-Bromo-4-(trifluoromethoxy)benzene
1-Bromo-4-(trifluoromethoxy)benzene was used in the synthesis of 4-{[4-[(2-ethylhexyloxy)-6-(4-morpholinylmethyl)-4-trifluoromethyl][1,1-biphenyl]-3-yl]methyl}morpholine.
Synthesis Reference(s)
Journal of the American Chemical Society, 109, p. 3708, 1987 DOI: 10.1021/ja00246a030
General Description
1-Bromo-4-(trifluoromethoxy)benzene on treatment with lithium diisopropylamide (LIDA) at -100°C gives 5-bromo-2-(trifluoromethoxy)phenyllithium and at -75°C it eliminates lithium bromide, thus generating 1,2-dehydro-4-(trifluoromethoxy)benzene.
Properties of 1-Bromo-4-(trifluoromethoxy)benzene
| Boiling point: | 80 °C50 mm Hg(lit.) |
| Density | 1.622 g/mL at 25 °C(lit.) |
| vapor pressure | 20 hPa (55 °C) |
| refractive index | n |
| Flash point: | 154 °F |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | 11.7mg/l |
| form | Liquid |
| color | Clear colorless to yellow |
| Specific Gravity | 1.64 |
| BRN | 2046332 |
| InChI | InChI=1S/C7H4BrF3O/c8-5-1-3-6(4-2-5)12-7(9,10)11/h1-4H |
| CAS DataBase Reference | 407-14-7(CAS DataBase Reference) |
| NIST Chemistry Reference | P-bromophenyl trifluoromethyl ether(407-14-7) |
Safety information for 1-Bromo-4-(trifluoromethoxy)benzene
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation |
| Precautionary Statement Codes |
P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P332+P313:IF SKIN irritation occurs: Get medical advice/attention. |
Computed Descriptors for 1-Bromo-4-(trifluoromethoxy)benzene
| InChIKey | SEAOBYFQWJFORM-UHFFFAOYSA-N |
| SMILES | C1(Br)=CC=C(OC(F)(F)F)C=C1 |
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product: 407-14-7 4-(trifluoromethoxy) bromobenzene 98%
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