(-)-MENTHYL CHLOROFORMATE
Synonym(s):(−)-Menthyl chloroformate
- CAS NO.:14602-86-9
- Empirical Formula: C11H19ClO2
- Molecular Weight: 218.72
- MDL number: MFCD00009694
- EINECS: 672-624-7
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-06-08 17:06:36
What is (-)-MENTHYL CHLOROFORMATE?
The Uses of (-)-MENTHYL CHLOROFORMATE
Readily forms a chloroimidodicarbonate which asymmetrically chlorinates silyl enol ethers under mild conditions and in good yields.
What are the applications of Application
(1R)-(?)-Menthyl chloroformate is a chiral derivatizing agent useful in GC, HPLC, and crystalization
Properties of (-)-MENTHYL CHLOROFORMATE
Boiling point: | 108-109 °C11 mm Hg(lit.) |
Density | 1.031 g/mL at 20 °C(lit.) |
vapor pressure | 0.01 psi ( 20 °C) |
refractive index | n |
Flash point: | 158 °F |
storage temp. | 2-8°C |
solubility | Chloroform (Sparingly), Methanol (Sparingly) |
form | clear liquid |
color | Colorless to Almost colorless |
optical activity | [α]20/D 83°, c = 1 in chloroform |
Sensitive | Moisture Sensitive |
BRN | 2414686 |
CAS DataBase Reference | 14602-86-9(CAS DataBase Reference) |
Safety information for (-)-MENTHYL CHLOROFORMATE
Signal word | Danger |
Pictogram(s) |
Corrosion Corrosives GHS05 Skull and Crossbones Acute Toxicity GHS06 |
GHS Hazard Statements |
H314:Skin corrosion/irritation H331:Acute toxicity,inhalation |
Precautionary Statement Codes |
P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for (-)-MENTHYL CHLOROFORMATE
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Diisopropyl chlorophosphate
4-Nitrophenyl chloroformate
CHLOROMETHYL CYCLOHEXYL ETHER
CHLOROMETHYL PROPYL ETHER
Chloromethyl methyl ether
2,5-DIMETHYLCYCLOHEXANOL
Isobutyl formate
DL-Menthol
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