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HomeProduct name list(+)-ALPHA-LONGIPINENE

(+)-ALPHA-LONGIPINENE

Synonym(s):(1R,2S,7R,8R)-2,6,6,9-Tetramethyltricyclo[5.4.0.02.8]undec-9-ene

(+)-ALPHA-LONGIPINENE Structural

What is (+)-ALPHA-LONGIPINENE?

The Uses of (+)-ALPHA-LONGIPINENE

(+)-α-Longipinene can be used as a starting material for the synthesis of new terpenoids, (+)-(5S)-5,12-dihydroxy-α-longipinene, (-)-(5R)-5,12-dihydroxy-α-longipinene, and (+)-12-hydroxy-α-longipinen-5-one by oxidation reaction using Aspergillus niger as a biocatalyst. It can be oxidized using lead tetraacetate into tertiary alcohol, longi-cis-verbenol, longi-trans-verbenol, longi-cis-β-crysanthenol, longiverbenone, longi-trans- β -crysanthenol, 2 β,3 β -dihydroxylongipinane, 4 α,8-dihydroxy- α -Iongipinene, and 4 β,8-dihydroxy- α -longipinene.

Definition

ChEBI: A bridged compound and sesquiterpene that is tricyclo[5.4.0.02,8]undecane that is substituted by methyl groups at the 2, 6, 6, and 9 positions and has a double bond between positions 9 and 10.

Properties of (+)-ALPHA-LONGIPINENE

Boiling point: 244-246 °C(lit.)
Density  0.915 g/mL at 20 °C(lit.)
refractive index  n20/D 1.493
Flash point: 92℃
storage temp.  2-8°C
solubility  Chloroform (Slightly), Dichloromethane (Slightly), Methanol (Slightly)
form  Oil
color  Colourless
optical activity [α]20/D +25±1°, neat
Stability: Light Sensitive

Safety information for (+)-ALPHA-LONGIPINENE

Computed Descriptors for (+)-ALPHA-LONGIPINENE

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