(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE
Synonym(s):(3aS,3′aS,8aR,8′aR)-2,2′-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole;(3aS,8aR)-in-pybox
- CAS NO.:185346-09-2
- Empirical Formula: C25H19N3O2
- Molecular Weight: 393.44
- MDL number: MFCD05861599
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE?
Chemical properties
White powder
The Uses of (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE
Reactant involved in synthesis of:
- Chiral ruthenium(II)-pybox complexes for use as intramolecular C-H amination catalysts
- Bis(oxazolinyl_pyridine-scandium(III) triflate complex catalyst for enantioselective addition of pyrroles to indoles
- Chiral N,N,N-tridentate pybos and pyboxazine ligands
Properties of (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE
Melting point: | 265°C (dec.) |
Boiling point: | 633.0±55.0 °C(Predicted) |
alpha | -364.0° (c 1.04, CH2Cl2) |
Density | 1.50±0.1 g/cm3(Predicted) |
storage temp. | Sealed in dry,Room Temperature |
form | Powder |
pka | 4.35±0.20(Predicted) |
color | white to off-white |
optical activity | [α]20/D -375°, c = 1 in dichloromethane (typical) |
Safety information for (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H302:Acute toxicity,oral |
Precautionary Statement Codes |
P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE
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