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HomeProduct name list2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine

2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine

Synonym(s):(S,S)-2,6-Bis(4,5-dihydro-4-phenyl-2-oxazolyl)pyridine;(S,S)-2,6-Bis(4-phenyl-2-oxazolinyl)pyridine

2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine Structural

What is 2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine?

Chemical properties

White solid

What are the applications of Application

2,6-Bis[(4S)-4-phenyl-2-oxazolinyl]pyridine is used in chemical synthesis

Reactions

1. Ligand for Copper catalyzed syn-selective Mukaiyama aldol reaction.
2. Ligand for Tin catalyzed anti-selective aldol reaction.
3. Ligand for Ytterbuim catalyzed desymmetrization of meso epoxides.
4. Ligand for Copper catalyzed enantioselective addition of terminal alkynes to imines.
5. Ligand for Scandium catalyzed enantioselective syn-selective ene reactions.
6. Ligand for Copper catalysed asymmetric alkynylation of cyclic azomethine Imines.
7. Ligand for Europium catalyzed asymmetric alpha amination.
8. Ligand for Indium catalyzed enantioselective construction of spiro-fused 2-oxindole/α-methylene-γ-butyrolactones.
9. Ligand for Copper catalyzed asymmetric azide-alkyne cycloaddition to quaternary oxindoles.
10. Ligand for Iron catalyzed enantioselective nitrene transfer to sulfides.
11. Ligand for Copper catalyzed enantioselective intramolecular propargylic amination.
12. Ligand for Copper catalyzed asymmetric hydroxylation.
13. Ligand for Scandium catalyzed dearomatization of 2-naphthols by electrophilic amination.
14. Ligand for Copper catalyzed asymmetric alkynylation of oxocarbenium ions to set diaryl tetrasubstituted stereoceters.
Reactions of 174500-20-0_1
Reactions of 174500-20-0_2
Reactions of 174500-20-0_3

Properties of 2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine

Melting point: 171-175 °C(lit.)
Boiling point: 600.4±55.0 °C(Predicted)
alpha  -224 º (c=1, chloroform)
Density  1.28±0.1 g/cm3(Predicted)
storage temp.  Inert atmosphere,Room Temperature
form  crystal
pka 3.07±0.70(Predicted)
color  white
optical activity [α]20/D 224°, c = 1 in chloroform
Water Solubility  Insoluble
CAS DataBase Reference 174500-20-0(CAS DataBase Reference)

Safety information for 2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine

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