2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&
Synonym(s):(3aR,3′aR,8aS,8′aS)-2,2′-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole;(3aR,8aS)-in-pybox
- CAS NO.：357209-32-6
- Empirical Formula: C25H19N3O2
- Molecular Weight: 393.44
- MDL number: MFCD09265074
- SAFETY DATA SHEET (SDS)
What is 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&?
Chemical properties
White powder
The Uses of 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&
Catalytic ligand used for:
- [3+2] cycloaddition of N-tosyl aziridines with electron-rich alkenes via selective carbon-carbon bond cleavage
- Enantioselective Mukaiyama-aldol reactions
- Enantioselective carbonyl-ene reactions
- Cu(I)-catalyzed asymmetric alkynylation of imino esters with terminal alkynes
- Asymmetric three-component coupling reactions catalyzed by a Cu/pybox complex
- Enantioselective Diels-Alder reaction
- Ni-catalyzed cross-coupling reactions
Properties of 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&
| Melting point: | 284 °C (dec.) |
| Boiling point: | 633.0±55.0 °C(Predicted) |
| Density | 1.50±0.1 g/cm3(Predicted) |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| pka | 4.35±0.20(Predicted) |
| optical activity | [α]20/D +386°, c = 1 in methylene chloride(lit.) |
Safety information for 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H302:Acute toxicity,oral |
| Precautionary Statement Codes |
P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&
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