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HomeProduct name list2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&

2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&

Synonym(s):(3aR,3′aR,8aS,8′aS)-2,2′-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole;(3aR,8aS)-in-pybox

2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& Structural

What is 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&?

Chemical properties

White powder

The Uses of 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&

Catalytic ligand used for:

  • [3+2] cycloaddition of N-tosyl aziridines with electron-rich alkenes via selective carbon-carbon bond cleavage
  • Enantioselective Mukaiyama-aldol reactions
  • Enantioselective carbonyl-ene reactions
  • Cu(I)-catalyzed asymmetric alkynylation of imino esters with terminal alkynes
  • Asymmetric three-component coupling reactions catalyzed by a Cu/pybox complex
  • Enantioselective Diels-Alder reaction
  • Ni-catalyzed cross-coupling reactions

Properties of 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&

Melting point: 284 °C (dec.)
Boiling point: 633.0±55.0 °C(Predicted)
Density  1.50±0.1 g/cm3(Predicted)
storage temp.  under inert gas (nitrogen or Argon) at 2-8°C
pka 4.35±0.20(Predicted)
optical activity [α]20/D +386°, c = 1 in methylene chloride(lit.)

Safety information for 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H302:Acute toxicity,oral
Precautionary Statement Codes P280:Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&

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