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7681-52-9

7681-52-9 structural image
Product Name: Sodium hypochlorite
Formula: ClNaO
Synonyms: bleach;Soda bleaching lye, Eau de Labarraque
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Sodium hypochlorite appears as colorless or slightly yellow watery liquid with an odor of household bleach. Mixes with water. (USCG, 1999)
Color/Form Greenish yellow liquid
Odor Disagreeable, sweetish odor
Boiling Point Boiling point: 111 °C in solution
Melting Point MP: 18 °C /Pentahydrate/
Solubility 29.3 g/100 g (0 °C) in water
Density 1.093 for 5% solution (USCG, 1999) - Denser than water; will sink
Vapor Pressure Vapor pressure, kPa at 20 °C: 2 - 2.5
Stability/Shelf Life UNSTABLE IN AIR UNLESS MIXED WITH SODIUM HYDROXIDE.
Decomposition The anhydrous solid obtained by dessication of the /sodium hypochlorite/ pentahydrate will decomp violently on heating or friction.
Odor Threshold The estimated odor threshold is the same as chlorine, 0.3 ppm
Other Experimental Properties Does not produce red color with phenolphthalein; colorless or slightly yellow liq /Sodium hypochlorite soln, diluted/
Chemical Classes Other Uses -> Biocides/Disinfectants

SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Corrosion
Corrosives
GHS05

Environment
GHS09
GHS Hazard Statements H314:Skin corrosion/irritation
H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P363:Wash contaminated clothing before reuse.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

COMPUTED DESCRIPTORS

Molecular Weight 74.44 g/mol
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 1
Rotatable Bond Count 0
Exact Mass 73.9535366 g/mol
Monoisotopic Mass 73.9535366 g/mol
Topological Polar Surface Area 23.1 Ų
Heavy Atom Count 3
Formal Charge 0
Complexity 4.8
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 2
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Sodium hypochlorite is generally used dissolved in water at various concentrations. Although available, solid sodium hypochlorite is not commercially used. Sodium hypochlorite solutions are clear, greenish to yellow liquids with an odor of chlorine. Calcium hypochlorite is a white solid that readily decomposes in water releasing oxygen and chlorine. It also has a strong chlorine odor. Neither compound occur naturally in the environment. Sodium and calcium hypochlorite are used primarily as bleaching agents or disinfectants. They are components of commercial bleaches, cleaning solutions, and disinfectants for drinking water and waste water purification systems and swimming pools.

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