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102-82-9

102-82-9 structural image
Product Name: Tributylamine
Formula: C12H27N
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Tributylamine appears as a pale yellow liquid with an ammonia-like odor. Less dense than water. Very irritating to skin, mucous membranes, and eyes. May be toxic by skin absorption. Low toxicity. Used as an inhibitor in hydraulic fluids.
Color/Form Pale yellow liquid
Odor Odor of ammonia
Boiling Point 415 °F at 760 mmHg (NTP, 1992)
Melting Point -94 °F (NTP, 1992)
Flash Point 185 °F (NTP, 1992)
Solubility Slightly soluble (NTP, 1992)
Density 0.7771 at 68 °F (NTP, 1992) - Less dense than water; will float
Vapor Density 6.38 (NTP, 1992) - Heavier than air; will sink (Relative to Air)
Vapor Pressure 20 mmHg at 212 °F (NTP, 1992)
LogP log Kow = 4.46
Stability/Shelf Life Stable under recommended storage conditions.
Autoignition Temperature 210 °C
Decomposition When heated to decomp, emits toxic fumes of /nitrogen oxides/.
Viscosity 1.35 cP at 25 °C; 0.73 cP at 60 °C
Heat of Vaporization 12,390.6 gcal/gmole
Surface Tension 24.9 dynes/cm at 20 °C
Ionization Efficiency Positive
Odor Threshold 8 female and 8 male volunteers were exposed to the test substance (> 99.5% pure) in varying concentrations. An odor threshold of 0.07 +/- 0.03 ppm (approx. 0.54 mg/cu m) was identified in this study (lowest value: 0.01 ppm)
Refractive Index Index of refraction: 1.4299 at 20 °C/D
Dissociation Constants pKa = 10.89
Kovats Retention Index 1192 1226 1228 1228 1189
Other Experimental Properties Conversion factors: 1 mg/L is equiv to 132 ppm; 1 ppm is equiv to 7.58 mg/cu m
Chemical Classes Nitrogen Compounds -> Amines, Aliphatic

SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Skull and Crossbones
Acute Toxicity
GHS06

Health Hazard
GHS08
GHS Hazard Statements H302:Acute toxicity,oral
H315:Skin corrosion/irritation
H372:Specific target organ toxicity, repeated exposure
Precautionary Statement Codes P262:Do not get in eyes, on skin, or on clothing.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P314:Get medical advice/attention if you feel unwell.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

COMPUTED DESCRIPTORS

Molecular Weight 185.35 g/mol
XLogP3 4
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 1
Rotatable Bond Count 9
Exact Mass 185.214349865 g/mol
Monoisotopic Mass 185.214349865 g/mol
Topological Polar Surface Area 3.2 Ų
Heavy Atom Count 13
Formal Charge 0
Complexity 72.1
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 1
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Tributylamine appears as a pale yellow liquid with an ammonia-like odor. Less dense than water. Very irritating to skin, mucous membranes, and eyes. May be toxic by skin absorption. Low toxicity. Used as an inhibitor in hydraulic fluids.