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HomeProduct name listTRIS(PENTAFLUOROPHENYL)BORANE

TRIS(PENTAFLUOROPHENYL)BORANE

Synonym(s):Perfluorotriphenylboron

  • CAS NO.:1109-15-5
  • Empirical Formula: C18BF15
  • Molecular Weight: 511.98
  • MDL number: MFCD00269813
  • EINECS: 000-000-0
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-07-14 20:44:35
TRIS(PENTAFLUOROPHENYL)BORANE Structural

What is TRIS(PENTAFLUOROPHENYL)BORANE?

Chemical properties

white powder

The Uses of TRIS(PENTAFLUOROPHENYL)BORANE

Tris(pentafluorophenyl)borane is used as an excellent activator component in homogeneous Ziegler-Natta chemistry. It is also used as a catalyst for reductions, alkylations, hydrometallation reactions and catalyzed aldol-type reactions. It is a useful Lewis acid and catalyzes hydrosilylation of aldehydes. Further, it is used in olefin polymerization catalysis. It serves as a reagent in the preparation of organometallic complexes. In addition to this, it is useful as polymerization catalysts and used to study the heterolytic cleavage of dihydrogen in associated with tri-tert-butylphosphine.

The Uses of TRIS(PENTAFLUOROPHENYL)BORANE

Catalyst in organic transformations; cocatalyst with group IV metallocene alkyls in olefin polymerization.

What are the applications of Application

Tris(pentafluorophenyl)borane is a useful component of Ziegler-Nattametallocene catalysts

General Description

B(C6F5)3 is a Lewis acid, stronger than the inorganic parent molecule BF3. In contrast to the prominent Lewis acids, the pentafluorides of the heavier elements of group 15, B(C6F5)3 has no oxidizing properties. B(C6F5)3 forms adducts with neutral and weaker Lewis bases. B(C6F5)3 has the capability to easily accept anionic ligands bonded to metals.

Properties of TRIS(PENTAFLUOROPHENYL)BORANE

Melting point: 126-131 °C (lit.)
Boiling point: 327.3±42.0 °C(Predicted)
Density  0.73 g/mL at 20 °C
refractive index  n20/D 1.41
Flash point: 7 °C
storage temp.  Inert atmosphere,Store in freezer, under -20°C
solubility  Soluble in hexane, chloroform, dichloromethane, toluene, and polar solvents.
form  Powder
color  White to light yellow-beige
Specific Gravity 1.7
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
λmax 306nm(Toluene)(lit.)
Sensitive  Moisture Sensitive
Merck  14,9755
BRN  2931347
CAS DataBase Reference 1109-15-5(CAS DataBase Reference)
EPA Substance Registry System Borane, tris(2,3,4,5,6-pentafluorophenyl)- (1109-15-5)

Safety information for TRIS(PENTAFLUOROPHENYL)BORANE

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for TRIS(PENTAFLUOROPHENYL)BORANE

InChIKey OBAJXDYVZBHCGT-UHFFFAOYSA-N

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