Iridium(III) acetylacetonate
Synonym(s):Ir(acac)3
- CAS NO.:15635-87-7
- Empirical Formula: C15H21IrO6
- Molecular Weight: 489.54
- MDL number: MFCD00015353
- EINECS: 239-711-8
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-10-17 17:11:55
What is Iridium(III) acetylacetonate?
Chemical properties
orange-yellow crystalline powder, easily soluble in benzene and chloroform, slightly soluble in methanol and ethanol, insoluble in water. The melting point is 269°C, and the decomposition temperature is 290°C.
The Uses of Iridium(III) acetylacetonate
Iridium(III) acetylacetonate is used as a photoreducing agent, a precursor for preparing Ir-C thin film and a catalyst for hydrogenation of sulfur containing compounds. Used in various catalysis reactions in organic synthesis, including carbon nanostructures.
What are the applications of Application
(1) Using Ir(acac)3 as the precursor, the tomahawk coating is prepared by MOCVD technology, which has been widely used as the base material of the engine of missiles, rockets, cruisers, automobiles, etc.
(2) Using Ir(acac)3 as the deposition source, Ir-C cluster films were prepared on ZrO2 substrates, which have excellent electrochemical properties.
(3) Catalysts for hydrogenation of sulfur-containing aromatics.
(4) Strong photoreducing agent for phenylpyridine aqueous solution.
Reactions
Precursor for preparation heterogeneous catalyst on different supports for various catalytic applications: organic reactions ; water oxidation ; CO preferential oxidation ; oxygen evolution reactions;
CVD/ALD precursor for preparation of Ir and Ir2O3 films on different substrates.
Starting material for synthesis of phosphorescent iridium complexes bearing arylpyridine ligands.
Properties of Iridium(III) acetylacetonate
Melting point: | 269-271 °C(lit.) |
Boiling point: | 260°C/1mmHg |
storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
solubility | slightly soluble in H2O; soluble in toluene, chloroform,acetone, methanol |
form | Crystalline |
color | Orange-yellow |
Water Solubility | Insoluble in water; soluble in chloroform and benzene; slightly soluble in ethanol and methanol. |
Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
NIST Chemistry Reference | Iridium, tris(2,4-pentanedionato-o,o')-, (oc-6-11)-(15635-87-7) |
Safety information for Iridium(III) acetylacetonate
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 Health Hazard GHS08 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation H351:Carcinogenicity |
Precautionary Statement Codes |
P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P308+P313:IF exposed or concerned: Get medical advice/attention. |
Computed Descriptors for Iridium(III) acetylacetonate
InChIKey | HLYTZTFNIRBLNA-LNTINUHCSA-K |
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