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HomeProduct name listIridium(III) acetylacetonate

Iridium(III) acetylacetonate

Synonym(s):Ir(acac)3

  • CAS NO.:15635-87-7
  • Empirical Formula: C15H21IrO6
  • Molecular Weight: 489.54
  • MDL number: MFCD00015353
  • EINECS: 239-711-8
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-10-17 17:11:55
Iridium(III) acetylacetonate Structural

What is Iridium(III) acetylacetonate?

Chemical properties

orange-yellow crystalline powder, easily soluble in benzene and chloroform, slightly soluble in methanol and ethanol, insoluble in water. The melting point is 269°C, and the decomposition temperature is 290°C.

The Uses of Iridium(III) acetylacetonate

Iridium(III) acetylacetonate is used as a photoreducing agent, a precursor for preparing Ir-C thin film and a catalyst for hydrogenation of sulfur containing compounds. Used in various catalysis reactions in organic synthesis, including carbon nanostructures.

What are the applications of Application

(1) Using Ir(acac)3 as the precursor, the tomahawk coating is prepared by MOCVD technology, which has been widely used as the base material of the engine of missiles, rockets, cruisers, automobiles, etc.
(2) Using Ir(acac)3 as the deposition source, Ir-C cluster films were prepared on ZrO2 substrates, which have excellent electrochemical properties.
(3) Catalysts for hydrogenation of sulfur-containing aromatics.
(4) Strong photoreducing agent for phenylpyridine aqueous solution.

Reactions

Precursor for preparation heterogeneous catalyst on different supports for various catalytic applications: organic reactions ; water oxidation ; CO preferential oxidation ; oxygen evolution reactions;
CVD/ALD precursor for preparation of Ir and Ir2O3 films on different substrates.
Starting material for synthesis of phosphorescent iridium complexes bearing arylpyridine ligands.

Properties of Iridium(III) acetylacetonate

Melting point: 269-271 °C(lit.)
Boiling point: 260°C/1mmHg
storage temp.  under inert gas (nitrogen or Argon) at 2-8°C
solubility  slightly soluble in H2O; soluble in toluene, chloroform,acetone, methanol
form  Crystalline
color  Orange-yellow
Water Solubility  Insoluble in water; soluble in chloroform and benzene; slightly soluble in ethanol and methanol.
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
NIST Chemistry Reference Iridium, tris(2,4-pentanedionato-o,o')-, (oc-6-11)-(15635-87-7)

Safety information for Iridium(III) acetylacetonate

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
H351:Carcinogenicity
Precautionary Statement Codes P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313:IF exposed or concerned: Get medical advice/attention.

Computed Descriptors for Iridium(III) acetylacetonate

InChIKey HLYTZTFNIRBLNA-LNTINUHCSA-K

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